Note: Ingredients listed on restricted chemical lists
EC/CAS
202-974-4/101-77-9
Name of the chemical
4,4'- Diaminodiphenylmethane
Concentration
4,4'-Diaminobiphenylmethane Included in the Candidate List of...
General Information
Version
6.9
Revision date
2025-08-25
Product name
4,4′-Diaminodiphenylmethane
CAS No.
101-77-9
REACH No
A
Emergency telephone
+56 2 2581 4934
Icons in SDS
Company Information
company name
Merck S.A
e-mail address of the competent person responsible for the Safety Data Sheet
atencionclientes@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H301, H317, H341, H350, H370, H373, H400, H410
Hazard statements
Code
Statements
H301
Toxic if swallowed
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture Acute toxicity, (Category 3) H301: Toxic if swallowed Skin sensitisation, (Category H317: May cause an allergic skin reaction Germ cell mutagenicity, H341: Suspected of causing genetic Category 2) defects Carcinogenicity, (Category 1B) H350: May cause cancer Specific target organ toxicity - H370: Causes damage to organs. single exposure, (Category 1), Liver, eye - retina Specific target organ toxicity H373: May cause damage to organs repeated exposure, (Category 2), through prolonged or repeated exposure. Liver Short-term (acute) aquatic H400: Very toxic to aquatic life hazard, (Category 1) Long-term (chronic) aquatic H411: Toxic to aquatic life with long lasting hazard, (Category 2) effects.
Signal word
Danger Danger
Hazard statements
H301 Toxic if swallowed. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H350 May cause cancer. H370 Causes damage to organs (Liver, eye - retina). H373 May cause damage to organs (Liver) through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects. H301 Toxic if swallowed. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H350 May cause cancer. H370 Causes damage to organs.
Precautionary statements
P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P302 + P352 IF ON SKIN: Wash with plenty of water. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P302 + P352 IF ON SKIN: Wash with plenty of water.
Supplemental label elements
none Restricted to professional users. Reduced Labelling (<= 125 ml) none
Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
2.1 Classification of the substance or mixture
Acute toxicity, (Category 3) H301: Toxic if swallowed. Skin sensitisation, (Category 1) H317: May cause an allergic skin reaction. Germ cell mutagenicity, H341: Suspected of causing genetic (Category 2) defects. Carcinogenicity, (Category 1B) H350: May cause cancer. Specific target organ toxicity - H370: Causes damage to organs. single exposure, (Category 1), Liver, eye - retina Specific target organ toxicity - H373: May cause damage to organs repeated exposure, (Category 2), through prolonged or repeated exposure. Liver Short-term (acute) aquatic H400: Very toxic to aquatic life. hazard, (Category 1) Long-term (chronic) aquatic H411: Toxic to aquatic life with long lasting hazard, (Category 2) effects.