Phenol solution,1.0 M in THF

Merck Ltd.

Revision date : 2023-12-30

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GHS07 GHS02 GHS08 GHS05
Health risk rating 4
Safety risk rating 5
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

109-99-9

Name of the chemical

Tetrahydrofuran (618/2012)

Concentration

>=90-< 5-53 100%

EC/CAS

203-632-7/108-95-2

Name of the chemical

Phenol

Concentration

>=10-<20

General Information

Version

9.3

Revision date

2023-12-30

Product name

Phenol solution,1.0 M in THF

REACH No

This

1.2.2. Uses advised against

For R&D use only. Not for pharmaceutical, household or other uses

Emergency telephone

+81 (3)4531-1145, +81 (0)3 4520 9637

Icons in SDS

GHS02 GHS05 GHS07 GHS08

Company Information

company name

Merck Ltd.

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H302+H332, H314, H335, H336, H341, H351, H373, H412

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Flammable liquids, (Category 2) H225: Highly flammable liquid and vapor. Acute toxicity, (Category 4) H302: Harmful if swallowed. Acute toxicity, (Category 4) H332: Harmful if inhaled. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Germ cell mutagenicity, H341: Suspected of causing genetic (Category 2) defects. Carcinogenicity, (Category 2) H351: Suspected of causing cancer. Specific target organ toxicity - H335: May cause respiratory irritation. single exposure, (Category 3), Respiratory system Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, (Category 3), Central nervous system Specific target organ toxicity - H373: May cause damage to organs repeated exposure, (Category 2), through prolonged or repeated exposure. Nervous system, Kidney, Liver, Skin Long-term (chronic) aquatic H412: Harmful to aquatic life with long hazard, (Category 3) lasting effects.

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapor. H302 + H332 Harmful if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H373 May cause damage to organs (Nervous system, Kidney, Liver, Skin) through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H314 Causes severe skin burns and eye damage. H412 Harmful to aquatic life with long lasting effects.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental label elements

EUH019 May form explosive peroxides. Reduced Labeling (<= 125 ml) EUH019 May form explosive peroxides.

Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

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