Note: Ingredients listed on restricted chemical lists
EC/CAS
203-632-7/108-95-2
Name of the chemical
Phenol
Concentration
>=50-<70
EC/CAS
200-663-8/67-66-3
Name of the chemical
Chloroform
Concentration
>=30-<50
General Information
Version
7.14
Revision date
2025-03-11
Product name
Phenol
Emergency telephone
+81 (3)4531-1145, +81 (0)3 4520 9637
Icons in SDS
Company Information
company name
Merck Ltd.
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H301, H312, H312+H332, H314, H318, H332, H336, H341, H351, H361d, H372, H373, H411
Hazard statements
Code
Statements
H301
Toxic if swallowed
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture Acute toxicity, (Category 3) H301: Toxic if swallowed Acute toxicity, (Category 4) H332: Harmful if inhaled Acute toxicity, (Category 4) H312: Harmful in contact with skin Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage Serious eye damage, (Category H318: Causes serious eye damage Germ cell mutagenicity, H341: Suspected of causing genetic Category 2) defects Carcinogenicity, (Category 2) H351: Suspected of causing cancer Reproductive toxicity, (Category H361d: Suspected of damaging the unborn child Specific target organ toxicity - H336: May cause drowsiness or dizziness single exposure, (Category 3), Central nervous system Specific target organ toxicity - H372: Causes damage to organs through repeated exposure, (Category 1), prolonged or repeated exposure if Liver, Kidney swallowed Specific target organ toxicity - H373: May cause damage to organs repeated exposure, (Category 2), through prolonged or repeated exposure Nervous system, Kidney, Liver, Skin Long-term (chronic) aquatic H411: Toxic to aquatic life with long lasting hazard, (Category 2) effects
Signal word
Danger Danger
Hazard statements
H301 Toxic if swallowed. H312 + H332 Harmful in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H361d Suspected of damaging the unborn child. H372 Causes damage to organs (Liver, Kidney) through prolonged or repeated exposure if swallowed. H373 May cause damage to organs (Nervous system, Kidney, Liver, Skin) through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. For use in industrial installations only. Reduced Labeling (<= 125 ml) H301 Toxic if swallowed. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H372 Causes damage to organs through prolonged or repeated exposure if swallowed. H314 Causes severe skin burns and eye damage. H361d Suspected of damaging the unborn child.
Precautionary statements
P202 Do not handle until all safety precautions have been read and understood. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P202 Do not handle until all safety precautions have been read and understood. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental label elements
none none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Rapidly absorbed through skin., Vesicant.
2.1 Classification of the substance or mixture
Acute toxicity, (Category 3) H301: Toxic if swallowed. Acute toxicity, (Category 4) H332: Harmful if inhaled. Acute toxicity, (Category 4) H312: Harmful in contact with skin. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Germ cell mutagenicity, H341: Suspected of causing genetic (Category 2) defects. Carcinogenicity, (Category 2) H351: Suspected of causing cancer. Reproductive toxicity, (Category H361d: Suspected of damaging the unborn 2) child. Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, (Category 3), Central nervous system Specific target organ toxicity - H372: Causes damage to organs through repeated exposure, (Category 1), prolonged or repeated exposure if Liver, Kidney swallowed. Specific target organ toxicity - H373: May cause damage to organs repeated exposure, (Category 2), through prolonged or repeated exposure. Nervous system, Kidney, Liver, Skin Long-term (chronic) aquatic H411: Toxic to aquatic life with long lasting hazard, (Category 2) effects.