Methyl methanesulfonate for synthesis

Merck Ltd.

Revision date : 2023-12-30

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GHS09 GHS08 GHS06
Health risk rating 5
Safety risk rating 1
Environmental risk rating 4

General Information

Version

6.7

Revision date

2023-12-30

Product name

Methyl methanesulfonate for synthesis

CAS No.

66-27-3

REACH No

A

1.2.1 Relevant identified uses

Chemical production, Reagent for analysis

Emergency telephone

+81 (3)4531-1145, +81 (0)3 4520 9637

Icons in SDS

GHS06 GHS08 GHS09

Company Information

company name

Merck Ltd.

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H301, H315, H317, H319, H340, H351, H361fd, H373, H411

Hazard statements

Code

Statements

H301

Toxic if swallowed

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture Acute toxicity, (Category 3) H301: Toxic if swallowed Skin irritation, (Category 2) H315: Causes skin irritation Eye irritation, (Category 2) H319: Causes serious eye irritation Skin sensitization, (Category 1) H317: May cause an allergic skin reaction Germ cell mutagenicity, H340: May cause genetic defects Category 1B) Carcinogenicity, (Category 2) H351: Suspected of causing cancer Reproductive toxicity, (Category H361fd: Suspected of damaging fertility Suspected of damaging the unborn child Specific target organ toxicity - H373: May cause damage to organs repeated exposure, (Category 2), through prolonged or repeated exposure if Lungs inhaled Long-term (chronic) aquatic H411: Toxic to aquatic life with long lasting hazard, (Category 2) effects

Signal word

Danger Danger

Hazard statements

H301 Toxic if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H340 May cause genetic defects. H351 Suspected of causing cancer. H361fd Suspected of damaging fertility. Suspected of damaging the unborn child. H373 May cause damage to organs (Lungs) through prolonged or repeated exposure if inhaled. H411 Toxic to aquatic life with long lasting effects. Reduced Labeling (<= 125 ml) H301 Toxic if swallowed. H317 May cause an allergic skin reaction. H340 May cause genetic defects. H351 Suspected of causing cancer. H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.

Precautionary statements

P202 Do not handle until all safety precautions have been read and understood. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P302 + P352 IF ON SKIN: Wash with plenty of water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P202 Do not handle until all safety precautions have been read and understood. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P302 + P352 IF ON SKIN: Wash with plenty of water.

Supplemental label elements

none none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Acute toxicity, (Category 3) H301: Toxic if swallowed. Skin irritation, (Category 2) H315: Causes skin irritation. Eye irritation, (Category 2) H319: Causes serious eye irritation. Skin sensitization, (Category 1) H317: May cause an allergic skin reaction. Germ cell mutagenicity, H340: May cause genetic defects. (Category 1B) Carcinogenicity, (Category 2) H351: Suspected of causing cancer. Reproductive toxicity, (Category H361fd: Suspected of damaging fertility. 2) Suspected of damaging the unborn child. Specific target organ toxicity - H373: May cause damage to organs repeated exposure, (Category 2), through prolonged or repeated exposure if Lungs inhaled. Long-term (chronic) aquatic H411: Toxic to aquatic life with long lasting hazard, (Category 2) effects.

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