Ethyl chloroacetate for synthesis

Merck Ltd.

Revision date : 2025-08-29

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GHS09 GHS02 GHS06
Health risk rating 5
Safety risk rating 2
Environmental risk rating 4

General Information

Version

6.10

Revision date

2025-08-29

Product name

Ethyl chloroacetate for synthesis

CAS No.

105-39-5

REACH No

A

1.2.1 Relevant identified uses

Intermediate for use under strictly controlled conditions, Chemical for synthesis

Emergency telephone

+81 (0)3 4520 9637

Icons in SDS

GHS02 GHS06 GHS09

Company Information

company name

Merck Ltd.

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H301+H331, H310, H315, H317, H318, H400

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Flammable liquids, (Category 3) H226: Flammable liquid and vapour. Acute toxicity, (Category 3) H301: Toxic if swallowed. Acute toxicity, (Category 3) H331: Toxic if inhaled. Acute toxicity, (Category 2) H310: Fatal in contact with skin. Skin irritation, (Category 2) H315: Causes skin irritation. Serious eye damage, (Category H318: Causes serious eye damage. 1) Skin sensitisation, (Category 1) H317: May cause an allergic skin reaction. Short-term (acute) aquatic H400: Very toxic to aquatic life. hazard, (Category 1)

Signal word

Danger Danger

Hazard statements

H226 Flammable liquid and vapour. H301 + H331 Toxic if swallowed or if inhaled. H310 Fatal in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H400 Very toxic to aquatic life. H310 Fatal in contact with skin. H318 Causes serious eye damage. H317 May cause an allergic skin reaction. H301 + H331 Toxic if swallowed or if inhaled.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental label elements

none Reduced Labelling (<= 125 ml) none

Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

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