Allylmagnesium bromide solution

Merck Ltd.

Revision date : 2025-03-11

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GHS05 GHS07 GHS02
Health risk rating 3
Safety risk rating 5
Environmental risk rating 1

General Information

Version

7.1

Revision date

2025-03-11

Product name

Allylmagnesium bromide solution

1.2.2. Uses advised against

For R&D use only. Not for pharmaceutical, household or other uses

Emergency telephone

+81 (3)4531-1145, +81 (0)3 4520 9637

Icons in SDS

GHS02 GHS05 GHS07

Company Information

company name

Merck Ltd.

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H250, H260, H302, H314, H318, H336

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Flammable liquids, (Category 2) H225: Highly flammable liquid and vapor. Pyrophoric liquids, (Category 1) H250: Catches fire spontaneously if exposed to air. Substances and mixtures which H260: In contact with water releases in contact with water emit flammable gases which may ignite flammable gases, (Category 1) spontaneously. Acute toxicity, (Category 4) H302: Harmful if swallowed. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, (Category 3), Central nervous system

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapor. H250 Catches fire spontaneously if exposed to air. H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness. H250 Catches fire spontaneously if exposed to air. H314 Causes severe skin burns and eye damage.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Supplemental label elements

EUH014 Reacts violently with water. EUH019 May form explosive peroxides. Reduced Labeling (<= 125 ml) EUH014 Reacts violently with water. EUH019 May form explosive peroxides.

Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

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