General Information
Version
7.1
Revision date
2025-03-11
Product name
Allylmagnesium bromide solution
1.2.2. Uses advised against
For R&D use only. Not for pharmaceutical, household or other uses
Emergency telephone
+81 (3)4531-1145, +81 (0)3 4520 9637
Icons in SDS
Company Information
company name
Merck Ltd.
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H250, H260, H302, H314, H318, H336
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Flammable liquids, (Category 2) H225: Highly flammable liquid and vapor. Pyrophoric liquids, (Category 1) H250: Catches fire spontaneously if exposed to air. Substances and mixtures which H260: In contact with water releases in contact with water emit flammable gases which may ignite flammable gases, (Category 1) spontaneously. Acute toxicity, (Category 4) H302: Harmful if swallowed. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, (Category 3), Central nervous system
Signal word
Danger Danger
Hazard statements
H225 Highly flammable liquid and vapor. H250 Catches fire spontaneously if exposed to air. H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness. H250 Catches fire spontaneously if exposed to air. H314 Causes severe skin burns and eye damage.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Supplemental label elements
EUH014 Reacts violently with water. EUH019 May form explosive peroxides. Reduced Labeling (<= 125 ml) EUH014 Reacts violently with water. EUH019 May form explosive peroxides.
Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.