(Trimethylsilyl)diazomethane solution

Merck Life Science UK Limited

Revision date : 2024-09-02

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GHS09 GHS08 GHS06 GHS02
Health risk rating 5
Safety risk rating 3
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

203-777-6/110-54-3

Name of the chemical

n-Hexan (790/2009)

Concentration

>=50-<70

General Information

Version

6.11

Revision date

2024-09-02

Product name

(Trimethylsilyl)diazomethane solution

REACH No

This

1.2.2. Uses advised against

For R&D use only. Not for pharmaceutical, household or other uses

Emergency telephone

+44 (0)870 8200418

Icons in SDS

GHS02 GHS06 GHS08 GHS09

Company Information

company name

Merck Life Science UK Limited

e-mail address of the competent person responsible for the Safety Data Sheet

TechnicalService@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H304, H315, H330, H336, H350, H361f, H370, H372, H411

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

2.2 Label elements

Labelling

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H330 Fatal if inhaled. H336 May cause drowsiness or dizziness. H350 May cause cancer. H361f Suspected of damaging fertility. H370 Causes damage to organs (Lungs) if inhaled. H372 Causes damage to organs (Nervous system) through prolonged or repeated exposure if inhaled. H411 Toxic to aquatic life with long lasting effects. Reduced Labeling (<= 125 ml) H330 Fatal if inhaled. H350 May cause cancer. H370 Causes damage to organs if inhaled. H372 Causes damage to organs through prolonged or repeated exposure if inhaled. H304 May be fatal if swallowed and enters airways. H361f Suspected of damaging fertility.

Precautionary statements

P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P331 Do NOT induce vomiting. P202 Do not handle until all safety precautions have been read and understood. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P331 Do NOT induce vomiting.

Supplemental label elements

none none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Preliminary data indicates this product may be highly toxic or fatal if inhaled., Inhalation may provoke the following symptoms:, pulmonary edema, Symptoms may be delayed for hours after exposure.

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