d5-DG Internal Standard Mixture I

Sigma-Aldrich Chemical Pvt Limited

Revision date : 2026-08-14

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GHS02 GHS06 GHS08
Health risk rating 5
Safety risk rating 3
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

200-659-6/67-56-1

Name of the chemical

Methanol

Concentration

>=30-<50 603-001- >=10% 3-<10%

EC/CAS

203-625-9/108-88-3

Name of the chemical

Toluene

Concentration

>=30-<50 20%

General Information

Version

6.17

Revision date

2026-08-14

Product name

d5-DG Internal Standard Mixture I

1.2.2. Uses advised against

For R&D use only. Not for pharmaceutical, household or other uses

Icons in SDS

GHS02 GHS06 GHS08 M004 M010 M011 M017

Company Information

company name

Sigma-Aldrich Chemical Pvt Limited

e-mail address of the competent person responsible for the Safety Data Sheet

customerservice@avantiresearch.com, technical@avantiresearch.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H301, H301+H311+H331, H304, H311, H315, H331, H336, H361d, H370, H373, H412

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapour. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H361d Suspected of damaging the unborn child. H370 Causes damage to organs (Eyes). H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. H370 Causes damage to organs. H304 May be fatal if swallowed and enters airways. H412 Harmful to aquatic life with long lasting effects. H361d Suspected of damaging the unborn child. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.

Precautionary statements

P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing. P201 Obtain special instructions before use. P280 Wear protective gloves/ protective clothing. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor.

Response

P302 + P352 + P312 IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor.

Hazardous Ingredients

Methanol Toluene Reduced Labelling (<= 125 ml)

Supplemental label elements

none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Acute toxicity, Category 3 H301: Toxic if swallowed. Acute toxicity, Category 3 H331: Toxic if inhaled. Acute toxicity, Category 3 H311: Toxic in contact with skin. Skin irritation, Category 2 H315: Causes skin irritation. Reproductive toxicity, Category 2 H361d: Suspected of damaging the unborn child. Specific target organ toxicity - H370: Causes damage to organs. single exposure, Category 1, Eyes Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, Category 3, Central nervous system Specific target organ toxicity - H373: May cause damage to organs through repeated exposure, Category 2, prolonged or repeated exposure. Central nervous system Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters airways. Long-term (chronic) aquatic hazard, H412: Harmful to aquatic life with long Category 3 lasting effects.

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