Note: Ingredients listed on restricted chemical lists
EC/CAS
200-659-6/67-56-1
Name of the chemical
Methanol
Concentration
>=30-<50 603-001- >=10% 3-<10%
EC/CAS
203-625-9/108-88-3
Name of the chemical
Toluene
Concentration
>=30-<50 20%
General Information
Version
6.17
Revision date
2026-08-14
Product name
d5-DG Internal Standard Mixture I
1.2.2. Uses advised against
For R&D use only. Not for pharmaceutical, household or other uses
Icons in SDS
Company Information
company name
Sigma-Aldrich Chemical Pvt Limited
e-mail address of the competent person responsible for the Safety Data Sheet
customerservice@avantiresearch.com, technical@avantiresearch.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H301, H301+H311+H331, H304, H311, H315, H331, H336, H361d, H370, H373, H412
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture
Signal word
Danger Danger
Hazard statements
H225 Highly flammable liquid and vapour. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H361d Suspected of damaging the unborn child. H370 Causes damage to organs (Eyes). H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. H370 Causes damage to organs. H304 May be fatal if swallowed and enters airways. H412 Harmful to aquatic life with long lasting effects. H361d Suspected of damaging the unborn child. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
Precautionary statements
P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing. P201 Obtain special instructions before use. P280 Wear protective gloves/ protective clothing. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor.
Response
P302 + P352 + P312 IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor.
Hazardous Ingredients
Methanol Toluene Reduced Labelling (<= 125 ml)
Supplemental label elements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Acute toxicity, Category 3 H301: Toxic if swallowed. Acute toxicity, Category 3 H331: Toxic if inhaled. Acute toxicity, Category 3 H311: Toxic in contact with skin. Skin irritation, Category 2 H315: Causes skin irritation. Reproductive toxicity, Category 2 H361d: Suspected of damaging the unborn child. Specific target organ toxicity - H370: Causes damage to organs. single exposure, Category 1, Eyes Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, Category 3, Central nervous system Specific target organ toxicity - H373: May cause damage to organs through repeated exposure, Category 2, prolonged or repeated exposure. Central nervous system Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters airways. Long-term (chronic) aquatic hazard, H412: Harmful to aquatic life with long Category 3 lasting effects.