Note: Ingredients listed on restricted chemical lists
EC/CAS
109-99-9
Name of the chemical
Tetrahydrofuran (618/2012)
Concentration
>=70-<90 5-53
General Information
Version
6.9
Revision date
2023-12-20
Product name
Lithium triethylborohydride solution
Emergency telephone
800-789-767, +39-02-4555-7031, +39 02-6610-1029
Icons in SDS
Company Information
company name
Merck Life Science S.r.l
e-mail address of the competent person responsible for the Safety Data Sheet
serviziotecnico@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H260, H302, H314, H335, H351
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Flammable liquids, (Category 2) H225: Highly flammable liquid and vapor. Substances and mixtures which H260: In contact with water releases in contact with water emit flammable gases which may ignite flammable gases, (Category 1) spontaneously. Acute toxicity, (Category 4) H302: Harmful if swallowed. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Carcinogenicity, (Category 2) H351: Suspected of causing cancer. Specific target organ toxicity - H335: May cause respiratory irritation. single exposure, (Category 3),
Signal word
Danger Danger
Hazard statements
H225 Highly flammable liquid and vapor. H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H314 Causes severe skin burns and eye damage. H351 Suspected of causing cancer.
Precautionary statements
P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P201 Obtain special instructions before use. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor.
Supplemental label elements
EUH014 Reacts violently with water. EUH018 In use may form flammable/explosive vapor-air mixture. EUH019 May form explosive peroxides. Reduced Labeling (<= 125 ml) EUH014 Reacts violently with water. EUH018 In use may form flammable/explosive vapor-air mixture. EUH019 May form explosive peroxides.
Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
