Note: Ingredients listed on restricted chemical lists
EC/CAS
203-625-9/108-88-3
Name of the chemical
Toluene
Concentration
>=70-<90
General Information
Version
7.0
Revision date
2024-09-30
Product name
Trimethylaluminum solution
REACH No
This
Emergency telephone
+(34)-931768545
Icons in SDS
Company Information
company name
Merck Life Science S.L
e-mail address of the competent person responsible for the Safety Data Sheet
serviciotecnico@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H250, H260, H304, H314, H318, H336, H361d, H373, H412
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture Flammable liquids, (Category 2) H225: Highly flammable liquid and vapor Pyrophoric liquids, (Category 1) H250: Catches fire spontaneously if exposed to air Substances and mixtures which H260: In contact with water releases in contact with water emit flammable gases which may ignite flammable gases, (Category 1) spontaneously Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage Serious eye damage, (Category H318: Causes serious eye damage Reproductive toxicity, (Category H361d: Suspected of damaging the unborn child Specific target organ toxicity - H336: May cause drowsiness or dizziness single exposure, (Category 3), Central nervous system Specific target organ toxicity - H373: May cause damage to organs repeated exposure, (Category 2), through prolonged or repeated exposure Central nervous system Aspiration hazard, (Category 1) H304: May be fatal if swallowed and enters airways Long-term (chronic) aquatic H412: Harmful to aquatic life with long hazard, (Category 3) lasting effects
Signal word
Danger Danger
Hazard statements
H225 Highly flammable liquid and vapor. H250 Catches fire spontaneously if exposed to air. H260 In contact with water releases flammable gases which may ignite spontaneously. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness. H361d Suspected of damaging the unborn child. H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. H250 Catches fire spontaneously if exposed to air. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H412 Harmful to aquatic life with long lasting effects. H361d Suspected of damaging the unborn child.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental label elements
EUH014 Reacts violently with water. Reduced Labeling (<= 125 ml) EUH014 Reacts violently with water.
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
2.1 Classification of the substance or mixture
Flammable liquids, (Category 2) H225: Highly flammable liquid and vapor. Pyrophoric liquids, (Category 1) H250: Catches fire spontaneously if exposed to air. Substances and mixtures which H260: In contact with water releases in contact with water emit flammable gases which may ignite flammable gases, (Category 1) spontaneously. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Reproductive toxicity, (Category H361d: Suspected of damaging the unborn 2) child. Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, (Category 3), Central nervous system Specific target organ toxicity - H373: May cause damage to organs repeated exposure, (Category 2), through prolonged or repeated exposure. Central nervous system Aspiration hazard, (Category 1) H304: May be fatal if swallowed and enters airways. Long-term (chronic) aquatic H412: Harmful to aquatic life with long hazard, (Category 3) lasting effects.