General Information
Version
7.1
Revision date
2025-12-24
Product name
Zinc phosphide
CAS No.
1314-84-7
Emergency telephone
+49 (0)696 43508409
Icons in SDS
Company Information
company name
Sigma-Aldrich Chemie GmbH
e-mail address of the competent person responsible for the Safety Data Sheet
technischerservice@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H260, H300, H312, H400, H410
Hazard statements
Code
Statements
H260
In contact with water releases flammable gases which may ignite spontaneously
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture
Signal word
Danger Danger
Hazard statements
H260 In contact with water releases flammable gases which may ignite spontaneously. H300 Fatal if swallowed. H312 Harmful in contact with skin. H410 Very toxic to aquatic life with long lasting effects. EUH032 Contact with acids liberates very toxic gas. H300 Fatal if swallowed.
Supplemental label elements
EUH029 Contact with water liberates toxic gas. EUH029 Contact with water liberates toxic gas. EUH032 Contact with acids liberates very toxic gas.
Precautionary statements
P223 Do not allow contact with water. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
Response
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/ doctor if you feel unwell. Reduced Labelling (<= 125 ml)
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008) Substances and mixtures, which in H260: In contact with water releases contact with water, emit flammable flammable gases which may ignite gases, Category 1 spontaneously. Acute toxicity, Category 2 H300: Fatal if swallowed. Acute toxicity, Category 4 H312: Harmful in contact with skin. Short-term (acute) aquatic hazard, H400: Very toxic to aquatic life. Category 1 Long-term (chronic) aquatic hazard, H410: Very toxic to aquatic life with long Category 1 lasting effects.