Zinc phosphide

Sigma-Aldrich Chemie GmbH

Revision date : 2025-12-24

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GHS02 GHS06 GHS09
Health risk rating 5
Safety risk rating 4
Environmental risk rating 5

General Information

Version

7.1

Revision date

2025-12-24

Product name

Zinc phosphide

CAS No.

1314-84-7

Emergency telephone

+49 (0)696 43508409

Icons in SDS

GHS02 GHS06 GHS09 M004 M009 M017

Company Information

company name

Sigma-Aldrich Chemie GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

technischerservice@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H260, H300, H312, H400, H410

Hazard statements

Code

Statements

H260

In contact with water releases flammable gases which may ignite spontaneously

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger Danger

Hazard statements

H260 In contact with water releases flammable gases which may ignite spontaneously. H300 Fatal if swallowed. H312 Harmful in contact with skin. H410 Very toxic to aquatic life with long lasting effects. EUH032 Contact with acids liberates very toxic gas. H300 Fatal if swallowed.

Supplemental label elements

EUH029 Contact with water liberates toxic gas. EUH029 Contact with water liberates toxic gas. EUH032 Contact with acids liberates very toxic gas.

Precautionary statements

P223 Do not allow contact with water. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/ doctor if you feel unwell. Reduced Labelling (<= 125 ml)

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Substances and mixtures, which in H260: In contact with water releases contact with water, emit flammable flammable gases which may ignite gases, Category 1 spontaneously. Acute toxicity, Category 2 H300: Fatal if swallowed. Acute toxicity, Category 4 H312: Harmful in contact with skin. Short-term (acute) aquatic hazard, H400: Very toxic to aquatic life. Category 1 Long-term (chronic) aquatic hazard, H410: Very toxic to aquatic life with long Category 1 lasting effects.

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