Vinylmagnesium bromide solution

Hazard statements (CLP)

H225, H260, H302, H314, H335, H336, H351, H373

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification Flammable liquids Category 2 Substances and mixtures, which in contact with wa- ter, emit flammable gases Category 1 Acute toxicity (Oral) Category 4 Skin corrosion/irritation Category 1A Serious eye damage/eye irritation Category 1 Carcinogenicity Category 2 Specific target organ tox- icity - single exposure Category 3 (Respiratory system, Central nervous sys- tem) Specific target organ tox- icity - repeated exposure Category 2

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour. H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure.

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P260 Do not breathe mist or vapours. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P302 + P335 + P334 IF ON SKIN: Brush off loose par- ticles from skin. Immerse in cool water. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immedi- ately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cau- tiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P370 + P378 In case of fire: Use dry sand, dry chemi- cal or alcohol-resistant foam to extinguish.

Other hazards which do not result in classification

May form explosive peroxides.

2.1 Classification of the substance or mixture

Flammable liquids : Category 2 Substances and mixtures, : Category 1 which in contact with wa- ter, emit flammable gases Acute toxicity (Oral) : Category 4 Skin corrosion/irritation : Category 1A Serious eye damage/eye : Category 1 irritation Carcinogenicity : Category 2 Specific target organ tox- : Category 3 (Respiratory system, Central nervous sys- icity - single exposure tem) Specific target organ tox- : Category 2 icity - repeated exposure