General Information
Version
7.0
Revision date
2012-01-11
Product name
Zirconium(IV) chloride anhydrous, for synthesis
REACH No
is
1.2.1 Relevant identified uses
Chemical for synthesis For additional information on uses please refer to the Merck Chemicals
Icons in SDS
Company Information
company name
Merck KGaA
e-mail address of the competent person responsible for the Safety Data Sheet
prodsafe@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H302, H314
Hazard statements
Code
Statements
H302
Harmful if swallowed
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification
Signal word
Danger Danger
Hazard statements
H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. EUH014 Reacts violently with water. H314 Causes severe skin burns and eye damage. EUH014 Reacts violently with water.
Precautionary statements
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. Reduced labelling (≤125 ml) P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. CAS-No. 10026-11-6
2.2 Label elements
67/548/EEC or 1999/45/EC)
Hazard pictograms
C Corrosive C Corrosive
R-phrase(s)
14-22-34 Reacts violently with water. Harmful if swallowed. Causes burns. 22-34 Harmful if swallowed. Causes burns.
S-phrase(s)
8-26-36/37/39-45 Keep container dry. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). EC-No. 233-058-2 Reduced labelling (≤125 ml) 26-36/37/39-45 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
2.3 Other hazards
None known.
