Note: Ingredients listed on restricted chemical lists
EC/CAS
137-30-4
Name of the chemical
Ziram
Concentration
>= 90 - <= 100
General Information
Version
6.8
Revision date
2026-07-10
Product name
Ziram
CAS No.
137-30-4
1.2.1 Relevant identified uses
Laboratory chemicals, Synthesis of substances
Emergency telephone
800-424-9300, +1-703- 527-3887
Icons in SDS
Company Information
company name
Sigma-Aldrich Inc
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H302, H317, H318, H330, H335, H373, H410
Hazard statements
Code
Statements
H302
Harmful if swallowed
Section 2
SECTION 2: Hazards identification
Long term hazards
Category 1 aquatic hazard
Other hazards
None known
Signal word
Danger
Hazard statements
H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H330 Fatal if inhaled. H335 May cause respiratory irritation. H373 May cause damage to organs (Liver, Blood) through prolonged or repeated exposure if swallowed. H410 Very toxic to aquatic life with long lasting effects.
Prevention
P260 Do not breathe dust. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face protection. P284 Wear respiratory protection.
Response
P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P314 Get medical advice/ attention if you feel unwell. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P363 Wash contaminated clothing before reuse. P391 Collect spillage.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Disposal
P501 Dispose of contents/ container to an approved waste disposal plant.
2.1 Classification of the substance or mixture
(29 CFR 1910.1200) Hazards for the product as supplied Acute toxicity (Oral) : Category 4 Acute toxicity : Category 2 (Inhalation) Serious eye damage : Category 1 Skin sensitisation : Category 1 Specific target organ : Category 3 (Respiratory system) toxicity - single exposure Specific target organ : Category 2 (Liver, Blood) toxicity - repeated exposure (Oral) Short-term (acute) : Category 1 aquatic hazard Long-term (chronic) : Category 1 aquatic hazard Other hazards
