Note: Ingredients listed on restricted chemical lists
EC/CAS
200-838-9/75-09-2
Name of the chemical
Methylene chloride
Concentration
>=70-<90 20%
EC/CAS
206-616-8/358-23-6
Name of the chemical
Trifluoromethanesulfonic anhydride
Concentration
>=20-<30
General Information
Version
6.13
Revision date
2026-07-13
Product name
Trifluoromethanesulfonic anhydride solution
Icons in SDS
Company Information
company name
Sigma-Aldrich Chemical Pvt Limited
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H272, H314, H318, H335, H336, H351
Hazard statements
Code
Statements
H272
May intensify fire; oxidiser
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture
Signal word
Danger Danger
Hazard statements
H272 May intensify fire; oxidizer. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H351 Suspected of causing cancer. H314 Causes severe skin burns and eye damage.
Supplemental label elements
EUH014 Reacts violently with water. EUH014 Reacts violently with water.
Precautionary statements
P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P202 Do not handle until all safety precautions have been read and understood. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Response
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Hazardous Ingredients
Dichloromethane Perfluoromethanesulfonic anhydride Reduced Labelling (<= 125 ml)
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008) Oxidizing liquids, Category 2 H272: May intensify fire; oxidizer. Skin corrosion, Sub-category 1B H314: Causes severe skin burns and eye damage. Serious eye damage, Category 1 H318: Causes serious eye damage. Carcinogenicity, Category 2 H351: Suspected of causing cancer. Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, Category 3, Central nervous system Specific target organ toxicity - H335: May cause respiratory irritation. single exposure, Category 3,