Tributylphosphine solution

Hazard statements (CLP)

H227, H251, H314, H360, H412

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

Classification of the substance or mixture

Signal word

Danger

Hazard statements

H227 Combustible liquid. H251 Self-heating; may catch fire. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H360 May damage fertility or the unborn child. H412 Harmful to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P235 + P410 Keep cool. Protect from sunlight. P261 Avoid breathing mist or vapors. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P407 Maintain air gap between stacks/ pallets. P420 Store away from other materials. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

Lachrymator.

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) Flammable liquids (Category 4), H227 Self-heating chemicals (Category 1), H251 Skin corrosion (Category 1B), H314 Serious eye damage (Category 1), H318 Reproductive toxicity (Category 1B), H360 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Short-term (acute) aquatic hazard (Category 3), H402 Long-term (chronic) aquatic hazard (Category 3), H412 For the full text of the H-Statements mentioned in this Section, see Section 16.