Toluene

Merck Ltd.

Revision date : 2026-07-23

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GHS02 GHS08 GHS07
Health risk rating 4
Safety risk rating 3
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

General Information

Version

7.2

Revision date

2026-07-23

Product name

Toluene

CAS No.

108-88-3

REACH No

01-2119471310-51-XXXX

Emergency telephone

+81 (0)3 4520 9637

Icons in SDS

GHS02 GHS07 GHS08 M004 M009 M010 M017

Company Information

company name

Merck Ltd.

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H304, H315, H336, H361d, H373, H412

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H361d Suspected of damaging the unborn child. H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure if inhaled. H412 Harmful to aquatic life with long lasting effects. H304 May be fatal if swallowed and enters airways. H412 Harmful to aquatic life with long lasting effects. H361d Suspected of damaging the unborn child.

Precautionary statements

P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P202 Do not handle until all safety precautions have been read and understood. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P331 Do NOT induce vomiting.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P331 Do NOT induce vomiting. Reduced Labelling (<= 125 ml)

Supplemental label elements

none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Skin irritation, Category 2 H315: Causes skin irritation. Reproductive toxicity, Category 2 H361d: Suspected of damaging the unborn child. Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, Category 3, Central nervous system Specific target organ toxicity - H373: May cause damage to organs through repeated exposure, Category 2, prolonged or repeated exposure if inhaled. Central nervous system Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters airways. Long-term (chronic) aquatic hazard, H412: Harmful to aquatic life with long Category 3 lasting effects.

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