tert-Butyl hydroperoxide (70% solution in water) for synthesis

Merck KGaA

Revision date : 2019-10-10

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GHS02 GHS05 GHS06 GHS07 GHS09
Health risk rating 4
Safety risk rating 5
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

75-91-2

Name of the chemical

tert-Butylhydroperoxid (2016/1179)

Concentration

100%

General Information

Revision date

2019-10-10

Product name

tert-Butyl hydroperoxide (70% solution in water) for synthesis

CAS No.

75-91-2

REACH No

This

Icons in SDS

GHS02 GHS05 GHS06 GHS09

Company Information

company name

Merck KGaA

e-mail address of the competent person responsible for the Safety Data Sheet

prodsafe@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H242, H302, H302+H332, H311, H314, H317, H332, H411

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

CLP CLASSIFICATION

Flammable liquid, Category 3, H226 Organic peroxide, Type F, H242 Acute toxicity, Category 4, Oral, H302 Acute toxicity, Category 4, Inhalation, H332 Acute toxicity, Category 3, Dermal, H311 Skin corrosion, Category 1A, H314 Skin sensitisation, Category 1, H317 Long-term (chronic) aquatic hazard, Category 2, H411 For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

REGULATION (EC) No 1272/2008)

Signal word

Danger Danger

Hazard statements

H226 Flammable liquid and vapour. H242 Heating may cause a fire. H302 + H332 Harmful if swallowed or if inhaled. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. EUH044 Risk of explosion if heated under confinement. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction.

Prevention

P210 Keep away from heat. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician. Reduced labelling (≤125 ml)

Precautionary statements

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.

Contains

tert-Butyl hydroperoxide

2.3 Other hazards

None known.

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