Sodium sulfide

Sigma-Aldrich Inc

Revision date : 2026-07-13

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GHS02 GHS06 GHS05 GHS09
Health risk rating 4
Safety risk rating 5
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

1313-82-2

Name of the chemical

Disodium sulphide

Concentration

>= 90 - <= 100

General Information

Version

6.15

Revision date

2026-07-13

Product name

Sodium sulfide

CAS No.

1313-82-2

1.2.1 Relevant identified uses

Laboratory chemicals, Synthesis of substances

1.2.2. Uses advised against

The product is being supplied under the TSCA R&D Exemption

Emergency telephone

800-424-9300, +1-703- 527-3887

Icons in SDS

GHS02 GHS05 GHS06 GHS09 M004 M010 M011 M017 M022

Company Information

company name

Sigma-Aldrich Inc

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H251, H290, H301+H311, H314, H400

Hazard statements

Code

Statements

H251

Self-heating; may catch fire

Section 2

SECTION 2: Hazards identification

2.3 Other hazards

Contact with acids liberates toxic gas. Corrosive to the respiratory tract. Contact with acids liberates toxic gas.

Signal word

Danger

Hazard statements

H251 Self-heating: may catch fire. H290 May be corrosive to metals. H301 + H311 Toxic if swallowed or in contact with skin. H314 Causes severe skin burns and eye damage. H400 Very toxic to aquatic life.

Prevention

P234 Keep only in original container. P235 + P410 Keep cool. Protect from sunlight. P260 Do not breathe dust. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P362 Take off contaminated clothing and wash before reuse. P390 Absorb spillage to prevent material damage. P391 Collect spillage.

Storage

P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P406 Store in corrosive resistant container with a resistant inner liner. P407 Maintain air gap between stacks/ pallets. P420 Store away from other materials.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

2.1 Classification of the substance or mixture

(29 CFR 1910.1200) Hazards for the product as supplied Self-heating chemicals : Category 1 Corrosive to metals : Category 1 Acute toxicity (Oral) : Category 3 Acute toxicity (Dermal) : Category 3 Skin corrosion : Category 1B Serious eye damage : Category 1 Short-term (acute) : Category 1 aquatic hazard Other hazards Contact with acids liberates toxic gas. Corrosive to the respiratory tract. Contact with acids liberates toxic gas.

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