Note: Ingredients listed on restricted chemical lists
EC/CAS
231-667-8/7681-49-4
Name of the chemical
Sodium fluoride
Concentration
>=90-<=100
General Information
Version
6.10
Revision date
2026-07-14
Product name
Sodium fluoride
CAS No.
7681-49-4
REACH No
01-2119539420-47-XXXX
Emergency telephone
+49 (0)696 43508409
Icons in SDS
Company Information
company name
Sigma-Aldrich Chemie GmbH
e-mail address of the competent person responsible for the Safety Data Sheet
technischerservice@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H301, H315, H319
Hazard statements
Code
Statements
H301
Toxic if swallowed
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture
Signal word
Danger Danger
Hazard statements
H301 Toxic if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H301 Toxic if swallowed.
Supplemental label elements
EUH032 Contact with acids liberates very toxic gas. EUH032 Contact with acids liberates very toxic gas.
Precautionary statements
P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. P264 Wash skin thoroughly after handling. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
Response
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P302 + P352 IF ON SKIN: Wash with plenty of water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313 If skin irritation occurs: Get medical advice/ attention. Reduced Labelling (<= 125 ml)
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Strong hydrogen fluoride-releaser
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008) Acute toxicity, Category 3 H301: Toxic if swallowed. Skin irritation, Category 2 H315: Causes skin irritation. Eye irritation, Category 2 H319: Causes serious eye irritation.
