Semivolatile Acids Surrogate Spike Mix

Merck Ltd.

Revision date : 2026-08-31

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GHS02 GHS06 GHS08
Health risk rating 5
Safety risk rating 3
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

200-659-6/67-56-1

Name of the chemical

Methanol

Concentration

>=90-< 603-001- >=10% 3-<10%

EC/CAS

204-278-6/118-79-6

Name of the chemical

2,4,6-tribromophenol

Concentration

=1-<2,5

Listed in

EC/CAS

202-433-2/95-57-8

Name of the chemical

2-chlorophenol,2

Concentration

=1-<2,5

Listed in

General Information

Version

6.13

Revision date

2026-08-31

Product name

Semivolatile Acids Surrogate Spike Mix

Emergency telephone

+81 (0)3 4520 9637

Icons in SDS

GHS02 GHS06 GHS08 M004 M009 M010 M011

Company Information

company name

Merck Ltd.

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H301, H301+H311+H331, H311, H315, H317, H319, H331, H341, H370, H412

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapour. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H341 Suspected of causing genetic defects. H370 Causes damage to organs (Eyes, Central nervous system). H412 Harmful to aquatic life with long lasting effects. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H370 Causes damage to organs. H412 Harmful to aquatic life with long lasting effects. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.

Precautionary statements

Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor.

Hazardous Ingredients

Methanol Phenol-D6 2,4,6-Tribromophenol 2-chlorophenol Reduced Labelling (<= 125 ml)

Supplemental label elements

none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Acute toxicity, Category 3 H301: Toxic if swallowed. Acute toxicity, Category 3 H331: Toxic if inhaled. Acute toxicity, Category 3 H311: Toxic in contact with skin. Skin irritation, Category 2 H315: Causes skin irritation. Eye irritation, Category 2 H319: Causes serious eye irritation. Skin sensitisation, Category 1 H317: May cause an allergic skin reaction. Germ cell mutagenicity, Category 2 H341: Suspected of causing genetic defects. Specific target organ toxicity - H370: Causes damage to organs. single exposure, Category 1, Eyes, Central nervous system Long-term (chronic) aquatic hazard, H412: Harmful to aquatic life with long Category 3 lasting effects.

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