Note: Ingredients listed on restricted chemical lists
EC/CAS
233-046-7/10025-87-3
Name of the chemical
Phosphoryl trichloride
Concentration
>= 0,1 % - < 1 %
General Information
Version
9.7
Revision date
2010-12-13
Product name
Phosphorus trichloride for synthesis
REACH No
is
1.2.1 Relevant identified uses
Chemical for synthesis For additional information on uses please refer to the Merck Chemicals
Icons in SDS
Company Information
company name
Merck KGaA
e-mail address of the competent person responsible for the Safety Data Sheet
prodsafe@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H300, H300+H330, H314, H330, H373
Hazard statements
Code
Statements
H300
Fatal if swallowed
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification
Signal word
Danger
Hazard statements
H300 + H330 Fatal if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H373 May cause damage to organs through prolonged or repeated exposure. EUH014 Reacts violently with water. EUH029 Contact with water liberates toxic gas.
Precautionary statements
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. Index-No. 015-007-00-4
2.2 Label elements
67/548/EEC or 1999/45/EC)
Hazard pictograms
T+ Very toxic T+ Very toxic C Corrosive
R-phrase(s)
14-26/28-29-35- Reacts violently with water. Very toxic by inhalation and if 48/20 swallowed. Contact with water liberates toxic gas. Causes severe burns. Harmful: danger of serious damage to health by prolonged exposure through inhalation. 26/28-35-48/20 Very toxic by inhalation and if swallowed. Causes severe burns. Harmful: danger of serious damage to health by prolonged exposure through inhalation.
S-phrase(s)
7/8-26-28-36/37/39- Keep container tightly closed and dry. In case of contact with 45 eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). EC-No. 231-749-3 EC Label Reduced labelling (≤125 ml) 26-36/37/39-45-28 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). After contact with skin, wash immediately with plenty of water.
2.3 Other hazards
None known.
