Oxalyl chloride solution

Sigma-Aldrich Chemical Pvt Limited

Revision date : 2025-12-23

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GHS02 GHS06 GHS08 GHS05
Health risk rating 4
Safety risk rating 4
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

200-838-9/75-09-2

Name of the chemical

Methylene chloride

Concentration

>=70-<90 20%

General Information

Version

7.3

Revision date

2025-12-23

Product name

Oxalyl chloride solution

Icons in SDS

GHS02 GHS05 GHS06 GHS08 M004 M009 M011 M017

Company Information

company name

Sigma-Aldrich Chemical Pvt Limited

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H260, H302, H314, H317, H318, H331, H336, H351

Hazard statements

Code

Statements

H260

In contact with water releases flammable gases which may ignite spontaneously

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger Danger

Hazard statements

H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H331 Toxic if inhaled. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. EUH029 Contact with water liberates toxic gas. EUH071 Corrosive to the respiratory tract. H331 Toxic if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H314 Causes severe skin burns and eye damage.

Supplemental label elements

EUH014 Reacts violently with water. EUH014 Reacts violently with water. EUH029 Contact with water liberates toxic gas. EUH071 Corrosive to the respiratory tract.

Precautionary statements

P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Response

P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Hazardous Ingredients

Dichloromethane oxalyl chloride Reduced Labelling (<= 125 ml)

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Substances and mixtures, which in H260: In contact with water releases contact with water, emit flammable flammable gases which may ignite gases, Category 1 spontaneously. Acute toxicity, Category 4 H302: Harmful if swallowed. Acute toxicity, Category 3 H331: Toxic if inhaled. Skin corrosion, Sub-category 1B H314: Causes severe skin burns and eye damage. Serious eye damage, Category 1 H318: Causes serious eye damage. Skin sensitisation, Category 1 H317: May cause an allergic skin reaction. Carcinogenicity, Category 2 H351: Suspected of causing cancer. Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, Category 3, Central nervous system

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