Oxalyl chloride, ReagentPlus , ≥99%

Hazard statements (CLP)

H260, H302, H314, H317, H331

Code

Statements

H260

In contact with water releases flammable gases which may ignite spontaneously

SECTION 2: Hazards identification

GHS Classification Substances and mixtures, which in contact with wa- ter, emit flammable gases Category 1 Acute toxicity (Oral) Category 4 Acute toxicity (Inhalation) Category 3 Skin corrosion/irritation Sub-category 1B Serious eye damage/eye irritation Category 1 Skin sensitisation Category 1

Signal word

Danger

Hazard statements

H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H331 Toxic if inhaled.

Supplemental label elements

AUH014 Reacts violently with water. AUH029 Contact with water liberates toxic gas. AUH071 Corrosive to the respiratory tract.

Prevention

P223 Do not allow contact with water. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P261 Avoid breathing mist or vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this prod- uct. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be al- lowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P335 + P334 IF ON SKIN: Brush off loose par- ticles from skin. Immerse in cool water. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immedi- ately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cau- tiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P333 + P313 If skin irritation or rash occurs: Get medi- cal advice/ attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use dry sand, dry chemi- cal or alcohol-resistant foam to extinguish.

Storage

P402 + P404 Store in a dry place. Store in a closed container. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Substances and mixtures, : Category 1 which in contact with wa- ter, emit flammable gases Acute toxicity (Oral) : Category 4 Acute toxicity (Inhalation) : Category 3 Skin corrosion/irritation : Sub-category 1B Serious eye damage/eye : Category 1 irritation Skin sensitisation