n-Butyllithium solution

Hazard statements (CLP)

H225, H250, H260, H304, H314, H318, H336, H361f, H372, H411

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapour. H250 Catches fire spontaneously if exposed to air. H260 In contact with water releases flammable gases which may ignite spontaneously. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness. H361f Suspected of damaging fertility. H372 Causes damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. H250 Catches fire spontaneously if exposed to air. H372 Causes damage to organs through prolonged or repeated exposure. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H361f Suspected of damaging fertility.

Supplemental label elements

EUH014 Reacts violently with water. EUH014 Reacts violently with water.

Prevention

Precautionary P210 Keep away from heat, hot surfaces, sparks,

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331 Do NOT induce vomiting. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Hazardous Ingredients

Hydrocarbons, C6, n-alkanes, isoalkanes, cyclics, n-hexane rich Butyllithium Reduced Labelling (<= 125 ml)

Precautionary statements

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331 Do NOT induce vomiting. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Pyrophoric liquids, Category 1 H250: Catches fire spontaneously if exposed to air. Substances and mixtures, which in H260: In contact with water releases contact with water, emit flammable flammable gases which may ignite gases, Category 1 spontaneously. Skin corrosion, Sub-category 1B H314: Causes severe skin burns and eye damage. Serious eye damage, Category 1 H318: Causes serious eye damage. Reproductive toxicity, Category 2 H361f: Suspected of damaging fertility. Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, Category 3, Central nervous system Specific target organ toxicity - H372: Causes damage to organs through repeated exposure, Category 1 prolonged or repeated exposure. Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters airways. Long-term (chronic) aquatic hazard, H411: Toxic to aquatic life with long lasting Category 2 effects.