Methylmagnesium bromide solution

Merck Life Science (Pty) Ltd

Revision date : 2023-04-15

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GHS02 GHS07
Health risk rating 4
Safety risk rating 5
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

203-625-9/108-88-3

Name of the chemical

Toluene

Concentration

>=50-<70

EC/CAS

203-726-8/109-99-9

Name of the chemical

Tetrahydrofuran (618/2012)

Concentration

>=20-<25

General Information

Version

6.9

Revision date

2023-04-15

Product name

Methylmagnesium bromide solution

REACH No

This

Icons in SDS

GHS02 GHS07

Company Information

company name

Merck Life Science (Pty) Ltd

e-mail address of the competent person responsible for the Safety Data Sheet

Melissa.byrne@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H260, H304, H314, H318, H336, H351, H361d, H373, H412

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification

Aspiration hazard

Category 1), H304 Long-term (chronic) aquatic hazard (Category 3), H412 For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapor. H260 In contact with water releases flammable gases which may ignite spontaneously. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H361d Suspected of damaging the unborn child. H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. H351 Suspected of causing cancer. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H412 Harmful to aquatic life with long lasting effects. H361d Suspected of damaging the unborn child.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental label elements

EUH014 Reacts violently with water. EUH019 May form explosive peroxides. Reduced Labeling (<= 125 ml) EUH014 Reacts violently with water. EUH019 May form explosive peroxides.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

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