Methyllithium solution

Hazard statements (CLP)

H225, H250, H260, H302, H314, H336

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification Flammable liquids Category 2 Pyrophoric liquids Category 1 Substances and mixtures, which in contact with wa- ter, emit flammable gases Category 1 Acute toxicity (Oral) Category 4 Skin corrosion/irritation Sub-category 1B Serious eye damage/eye irritation Category 1 Specific target organ tox- icity - single exposure Category 3 (Central nervous system)

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour. H250 Catches fire spontaneously if exposed to air. H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness.

Supplemental label elements

AUH019 May form explosive peroxides.

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P222 Do not allow contact with air. P223 Do not allow contact with water. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P233 Keep container tightly closed. P240 Ground and bond container and receiving equip- ment. P241 Use explosion-proof electrical/ ventilating/ light- ing equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P261 Avoid breathing mist or vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this prod- uct. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P335 + P334 IF ON SKIN: Brush off loose par- ticles from skin. Immerse in cool water. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immedi- ately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cau- tiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemi- cal or alcohol-resistant foam to extinguish.

Storage

P402 + P404 Store in a dry place. Store in a closed container. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Flammable liquids : Category 2 Pyrophoric liquids : Category 1 Substances and mixtures, : Category 1 which in contact with wa- ter, emit flammable gases Acute toxicity (Oral) : Category 4 Skin corrosion/irritation : Sub-category 1B Serious eye damage/eye : Category 1 irritation Specific target organ tox- : Category 3 (Central nervous system) icity - single exposure