Methyl perfluorooctanoate

Sigma-Aldrich Chemical Pvt Limited

Revision date : 2026-08-12

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GHS08 GHS05 GHS07
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

206-808-1/376-27-2

Name of the chemical

Methylperfluorooctanoate

Concentration

>=90-<=100

General Information

Version

9.1

Revision date

2026-08-12

Product name

Methyl perfluorooctanoate

CAS No.

376-27-2

Icons in SDS

GHS05 GHS07 GHS08 M004 M009 M011 M017

Company Information

company name

Sigma-Aldrich Chemical Pvt Limited

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H302, H302+H332, H318, H332, H351, H360D, H362, H372

Hazard statements

Code

Statements

H302

Harmful if swallowed

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger Danger

Hazard statements

H302 + H332 Harmful if swallowed or if inhaled. H318 Causes serious eye damage. H351 Suspected of causing cancer. H360D May damage the unborn child. H362 May cause harm to breast-fed children. H372 Causes damage to organs (Liver) through prolonged or repeated exposure. H351 Suspected of causing cancer. H362 May cause harm to breast-fed children. H372 Causes damage to organs through prolonged or repeated exposure. H318 Causes serious eye damage. H360D May damage the unborn child.

Precautionary statements

Prevention: P263 Avoid contact during pregnancy and while nursing. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Response

P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. Reduced Labelling (<= 125 ml)

Supplemental label elements

none

2.3 Other hazards

This substance/mixture contains components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB).

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Acute toxicity, Category 4 H302: Harmful if swallowed. Acute toxicity, Category 4 H332: Harmful if inhaled. Serious eye damage, Category 1 H318: Causes serious eye damage. Carcinogenicity, Category 2 H351: Suspected of causing cancer. Reproductive toxicity, Category 1B H360D: May damage the unborn child. Effects on or via lactation H362: May cause harm to breast-fed children. Specific target organ toxicity - H372: Causes damage to organs through repeated exposure, Category 1, prolonged or repeated exposure. Liver

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