Note: Ingredients listed on restricted chemical lists
EC/CAS
106-49-0
Name of the chemical
p-Toluidin
Concentration
>=0.5-<=1.5
General Information
Version
8.12
Revision date
2025-12-31
Product name
m-Toluidine for synthesis
CAS No.
108-44-1
1.2.1 Relevant identified uses
Intermediate for use under strictly controlled conditions, Chemical for synthesis
1.2.2. Uses advised against
The product is being supplied under the TSCA R&D Exemption
Emergency telephone
800-424-9300, +1-703- 527-3887
Icons in SDS
Company Information
company name
Sigma-Aldrich Inc
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H227, H301+H311+H331, H317, H351, H373, H410
Hazard statements
Code
Statements
H227
Combustible liquid
Section 2
SECTION 2: Hazards identification
Long term hazards
Category 1 aquatic hazard
Other hazards
None known
Signal word
Danger
Hazard statements
H227 Combustible liquid. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects.
Prevention
P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response
P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391 Collect spillage.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.
Disposal
P501 Dispose of contents/ container to an approved waste disposal plant.
2.1 Classification of the substance or mixture
(29 CFR 1910.1200) Hazards for the product as supplied Flammable liquids : Category 4 Acute toxicity (Oral) : Category 3 Acute toxicity : Category 3 (Inhalation) Acute toxicity (Dermal) : Category 3 Skin sensitisation : Category 1 Carcinogenicity : Category 2 Specific target organ : Category 2 toxicity - repeated exposure Short-term (acute) : Category 1 aquatic hazard Long-term (chronic) : Category 1 aquatic hazard Other hazards
