Lithium diisopropylamide solution

Sigma-Aldrich Chemical Pvt Limited

Revision date : 2026-07-09

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GHS02 GHS08 GHS05 GHS07 GHS09
Health risk rating 5
Safety risk rating 5
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

223-893-0/109-99-9

Name of the chemical

Tetrahydrofuran (618/2012)

Concentration

>=20-<25 >=25% >=25%

EC/CAS

202-849-4/100-41-4

Name of the chemical

Ethylbenzene

Concentration

>=10-<20

Listed in

EC/CAS

203-558-5/108-18-9

Name of the chemical

N,N-Di-i-propylamine (2-Propanamine, N-(1-methylethyl)-)

Concentration

>=2,5-<3 >=5%

Listed in

EC/CAS

203-726-8

Name of the chemical

Tetrahydrofuran (618/2012)

Concentration

>=20-<25 >=25% >=25%

General Information

Version

8.3

Revision date

2026-07-09

Product name

Lithium diisopropylamide solution

Icons in SDS

GHS02 GHS05 GHS07 GHS08 GHS09 M004 M009 M010 M011 M017

Company Information

company name

Sigma-Aldrich Chemical Pvt Limited

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H304, H314, H318, H335, H336, H351, H360FD, H373, H400, H410

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H360FD May damage fertility. May damage the unborn child. H373 May cause damage to organs (hearing organs) through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects. EUH451 Can cause very long-lasting and diffuse contamination of water resources. EUH019 May form explosive peroxides. H351 Suspected of causing cancer. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. EUH451 Can cause very long-lasting and diffuse contamination of water resources. H360FD May damage fertility. May damage the unborn child.

Supplemental label elements

EUH014 Reacts violently with water. EUH014 Reacts violently with water. EUH019 May form explosive peroxides.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331 Do NOT induce vomiting. P391 Collect spillage. P501 Dispose of contents/ container to an approved waste disposal plant.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331 Do NOT induce vomiting. P391 Collect spillage.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Hazardous Ingredients

n-heptane lithium diisopropylamide Tetrahydrofuran ethylbenzene diisopropylamine Reduced Labelling (<= 125 ml)

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Skin corrosion, Sub-category 1B H314: Causes severe skin burns and eye damage. Serious eye damage, Category 1 H318: Causes serious eye damage. Carcinogenicity, Category 2 H351: Suspected of causing cancer. Reproductive toxicity, Category 1B H360FD: May damage fertility. May damage the unborn child. Specific target organ toxicity - H335: May cause respiratory irritation. single exposure, Category 3, Respiratory system Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, Category 3, Central nervous system Specific target organ toxicity - H373: May cause damage to organs through repeated exposure, Category 2, prolonged or repeated exposure. hearing organs Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters airways. Short-term (acute) aquatic hazard, H400: Very toxic to aquatic life. Category 1 Long-term (chronic) aquatic hazard, H410: Very toxic to aquatic life with long Category 1 lasting effects. Persistent, mobile and toxic EUH450: Can cause long-lasting and diffuse contamination of water resources. Very persistent and very mobile EUH451: Can cause very long-lasting and diffuse contamination of water resources.

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