Note: Ingredients listed on restricted chemical lists
EC/CAS
223-893-0/109-99-9
Name of the chemical
Tetrahydrofuran (618/2012)
Concentration
>=20-<25 >=25% >=25%
EC/CAS
202-849-4/100-41-4
Name of the chemical
Ethylbenzene
Concentration
>=10-<20
EC/CAS
203-558-5/108-18-9
Name of the chemical
N,N-Di-i-propylamine (2-Propanamine, N-(1-methylethyl)-)
Concentration
>=2,5-<3 >=5%
EC/CAS
203-726-8
Name of the chemical
Tetrahydrofuran (618/2012)
Concentration
>=20-<25 >=25% >=25%
General Information
Version
8.3
Revision date
2026-07-09
Product name
Lithium diisopropylamide solution
Icons in SDS
Company Information
company name
Sigma-Aldrich Chemical Pvt Limited
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H304, H314, H318, H335, H336, H351, H360FD, H373, H400, H410
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture
Signal word
Danger Danger
Hazard statements
H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H360FD May damage fertility. May damage the unborn child. H373 May cause damage to organs (hearing organs) through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects. EUH451 Can cause very long-lasting and diffuse contamination of water resources. EUH019 May form explosive peroxides. H351 Suspected of causing cancer. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. EUH451 Can cause very long-lasting and diffuse contamination of water resources. H360FD May damage fertility. May damage the unborn child.
Supplemental label elements
EUH014 Reacts violently with water. EUH014 Reacts violently with water. EUH019 May form explosive peroxides.
Precautionary statements
P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331 Do NOT induce vomiting. P391 Collect spillage. P501 Dispose of contents/ container to an approved waste disposal plant.
Response
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331 Do NOT induce vomiting. P391 Collect spillage.
Disposal
P501 Dispose of contents/ container to an approved waste disposal plant.
Hazardous Ingredients
n-heptane lithium diisopropylamide Tetrahydrofuran ethylbenzene diisopropylamine Reduced Labelling (<= 125 ml)
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Skin corrosion, Sub-category 1B H314: Causes severe skin burns and eye damage. Serious eye damage, Category 1 H318: Causes serious eye damage. Carcinogenicity, Category 2 H351: Suspected of causing cancer. Reproductive toxicity, Category 1B H360FD: May damage fertility. May damage the unborn child. Specific target organ toxicity - H335: May cause respiratory irritation. single exposure, Category 3, Respiratory system Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, Category 3, Central nervous system Specific target organ toxicity - H373: May cause damage to organs through repeated exposure, Category 2, prolonged or repeated exposure. hearing organs Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters airways. Short-term (acute) aquatic hazard, H400: Very toxic to aquatic life. Category 1 Long-term (chronic) aquatic hazard, H410: Very toxic to aquatic life with long Category 1 lasting effects. Persistent, mobile and toxic EUH450: Can cause long-lasting and diffuse contamination of water resources. Very persistent and very mobile EUH451: Can cause very long-lasting and diffuse contamination of water resources.