Lithium diisopropylamide solution

Hazard statements (CLP)

H225, H304, H314, H335, H336, H351, H360, H373, H410

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification Flammable liquids Category 2 Skin corrosion/irritation Sub-category 1B Serious eye damage/eye irritation Category 1 Carcinogenicity Category 2 Reproductive toxicity Category 1B Specific target organ tox- icity - single exposure Category 3 (Respiratory system, Central nervous sys- tem) Specific target organ tox- icity - repeated exposure Category 2 (hearing organs)

Aspiration hazard

Category 1 Short-term (acute) aquat- Category 1 ic hazard Long-term (chronic) Category 1 aquatic hazard

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H360 May damage fertility or the unborn child. H373 May cause damage to organs (hearing organs) through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects.

Supplemental label elements

AUH014 Reacts violently with water. AUH019 May form explosive peroxides.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equip- ment. P241 Use explosion-proof electrical/ ventilating/ light- ing equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe mist or vapours. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P301 + P330 + P331 + P310 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immedi- ately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cau- tiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P331 Do NOT induce vomiting. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemi- cal or alcohol-resistant foam to extinguish. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Flammable liquids : Category 2 Skin corrosion/irritation : Sub-category 1B Serious eye damage/eye : Category 1 irritation Carcinogenicity : Category 2 Reproductive toxicity : Category 1B Specific target organ tox- : Category 3 (Respiratory system, Central nervous sys- icity - single exposure tem) Specific target organ tox- : Category 2 (hearing organs) icity - repeated exposure Aspiration hazard : Category 1 Short-term (acute) aquat- : Category 1 ic hazard Long-term (chronic) : Category 1 aquatic hazard