General Information
Revision date
2021-07-01
Product name
Lithium bis(trimethylsilyl)amide for synthesis
CAS No.
4039-32-1
REACH No
is
Icons in SDS
Company Information
company name
Merck KGaA
e-mail address of the competent person responsible for the Safety Data Sheet
TechnicalService@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H228, H251, H314, H318
Hazard statements
Code
Statements
H228
Flammable solid
Section 2
CLP CLASSIFICATION
Flammable solids (Category 1), H228 Self-heating substances and mixtures (Category 1), H251 Skin corrosion (Sub-category 1B), H314 Serious eye damage (Category 1), H318 For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Signal word
Danger Danger
Hazard statements
H228 Flammable solid. H251 Self-heating; may catch fire. H314 Causes severe skin burns and eye damage. H251 Self-heating; may catch fire. H314 Causes severe skin burns and eye damage.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P235 Keep cool. P260 Do not breathe dusts or mists. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P235 Keep cool. P260 Do not breathe dusts or mists. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental label elements
EUH014 Reacts violently with water. Reduced Labeling (<= 125 ml) EUH014 Reacts violently with water.
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.