Lithium aluminum hydride solution

Sigma-Aldrich Chemie GmbH

Revision date : 2025-12-26

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GHS02 GHS08 GHS07
Health risk rating 5
Safety risk rating 5
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

General Information

Version

6.12

Revision date

2025-12-26

Product name

Lithium aluminum hydride solution

1.2.2. Uses advised against

For R&D use only. Not for pharmaceutical, household or other uses

Emergency telephone

+49 (0)696 43508409

Icons in SDS

GHS02 GHS07 GHS08 M004 M010 M017

Company Information

company name

Sigma-Aldrich Chemie GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

technischerservice@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H261, H315, H319, H360FD

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger Danger

Hazard statements

H226 Flammable liquid and vapour. H315 Causes skin irritation. H319 Causes serious eye irritation. H360FD May damage fertility. May damage the unborn child. H360FD May damage fertility. May damage the unborn child.

Supplemental label elements

EUH019 May form explosive peroxides. EUH019 May form explosive peroxides.

Precautionary statements

P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P202 Do not handle until all safety precautions have been read and understood. P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Hazardous Ingredients

Diethyleneglycol dimethylether Reduced Labelling (<= 125 ml)

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Substances, which in contact with H261: In contact with water releases water, emit flammable gases, flammable gases. Category 1 Flammable liquids, Category 3 H226: Flammable liquid and vapour. Skin irritation, Category 2 H315: Causes skin irritation. Eye irritation, Category 2 H319: Causes serious eye irritation. Reproductive toxicity, Category 1B H360FD: May damage fertility. May damage the unborn child.

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