General Information
Version
6.9
Revision date
2026-07-14
Product name
Isobutylmagnesium bromide solution
Emergency telephone
+81 (0)3 4520 9637
Icons in SDS
Company Information
company name
Merck Ltd.
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H224, H302, H315, H318, H336
Hazard statements
Code
Statements
H224
Extremely flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture
Signal word
Danger Danger
Hazard statements
H224 Extremely flammable liquid and vapour. H302 Harmful if swallowed. H315 Causes skin irritation. H318 Causes serious eye damage. H336 May cause drowsiness or dizziness. H224 Extremely flammable liquid and vapour. H318 Causes serious eye damage.
Supplemental label elements
EUH019 May form explosive peroxides. EUH019 May form explosive peroxides.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
Response
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
Hazardous Ingredients
Diethyl ether Isobutylmagnesium bromide Reduced Labelling (<= 125 ml)
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 1 H224: Extremely flammable liquid and vapour. Acute toxicity, Category 4 H302: Harmful if swallowed. Skin irritation, Category 2 H315: Causes skin irritation. Serious eye damage, Category 1 H318: Causes serious eye damage. Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, Category 3, Central nervous system