Hydroxylammonium chloride for synthesis

Merck KGaA

Revision date : 2013-02-18

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GHS05 GHS07 GHS08 GHS09
Health risk rating 4
Safety risk rating 5
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

5470-11-1

Name of the chemical

Hydroxylammoniumchlorid; Hydroxylaminhydrochlorid Bis(hydroxylammonium)sulfat; Hydroxylaminsulfat (2 : 1) (790/2009)

Concentration

N/A

EC/CAS

226-798-2

Name of the chemical

Hydroxylammoniumchlorid; Hydroxylaminhydrochlorid Bis(hydroxylammonium)sulfat; Hydroxylaminsulfat (2 : 1) (790/2009)

Concentration

N/A

General Information

Revision date

2013-02-18

Product name

Hydroxylammonium chloride for synthesis

CAS No.

5470-11-1

REACH No

is

Emergency telephone

Please contact the regional company representation in your country

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Company Information

company name

Merck KGaA

e-mail address of the competent person responsible for the Safety Data Sheet

prodsafe@merckgroup.com

GHS Information

Signal word

Warning

Hazard Codes

Hazard statements (CLP)

H290, H302, H302+H312, H312, H315, H317, H319, H351, H373, H400

Hazard statements

Code

Statements

H290

May be corrosive to metals

Section 2

CLP CLASSIFICATION

Acute toxicity, Category 4, Oral, H302 Acute toxicity, Category 4, Dermal, H312 Carcinogenicity, Category 2, H351 Skin irritation, Category 2, H315 Eye irritation, Category 2, H319 Skin sensitization, Category 1, H317 Specific target organ toxicity - repeated exposure, Category 2, Oral, H373 Acute aquatic toxicity, Category 1, H400 Corrosive to metals, Category 1, H290 For the full text of the H-Statements mentioned in this Section, see Section 16.

2.1 Classification of the substance or mixture

67/548/EEC or 1999/45/EC) E Explosive R2 Xn Harmful R21/22 - 48/22 Xi Irritant R36/38 R43 Carc.Cat.3 Carcinogenic Category 3 R40 N Dangerous for the environment R50 For the full text of the R-phrases mentioned in this Section, see Section 16.

2.2 Label elements

REGULATION (EC) No 1272/2008) (67/548/EEC or 1999/45/EC)

Signal word

Warning Warning

Hazard statements

H302 + H312 Harmful if swallowed or in contact with skin H351 Suspected of causing cancer. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H290 May be corrosive to metals. H351 Suspected of causing cancer. H317 May cause an allergic skin reaction.

Prevention

P273 Avoid release to the environment. P281 Use personal protective equipment as required.

Response

P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. Reduced labelling (≤125 ml)

Precautionary statements

P281 Use personal protective equipment as required. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P308 + P313 IF exposed or concerned: Get medical advice/ attention. Index-No. 612-123-00-2

Hazard pictograms

E Explosive Xn Harmful N Dangerous for the environment E Explosive Xn Harmful N Dangerous for the environment

R-phrase(s)

2-21/22-36/38-40- Risk of explosion by shock, friction, fire or other sources of 43-48/22-50 ignition. Harmful in contact with skin and if swallowed. Irritating to eyes and skin. Limited evidence of a carcinogenic effect. May cause sensitization by skin contact. Harmful: danger of serious damage to health by prolonged exposure if swallowed. Very toxic to aquatic organisms. 2-21/22-40-43-48/22 Risk of explosion by shock, friction, fire or other sources of ignition. Harmful in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. May cause sensitization by skin contact. Harmful: danger of serious damage to health by prolonged exposure if swallowed.

S-phrase(s)

36/37-61 Wear suitable protective clothing and gloves. Avoid release to the environment. Refer to special instructions/ Safety data sheets. EC-No. 226-798-2 EC Label Reduced labelling (≤125 ml) 36/37 Wear suitable protective clothing and gloves.

2.3 Other hazards

None known.

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