Hydrogen peroxide solution

Sigma-Aldrich Chemie GmbH

Revision date : 2026-07-13

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GHS03 GHS05 GHS07 GHS09
Health risk rating 3
Safety risk rating 4
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

231-765-0/7722-84-1

Name of the chemical

Hydrogen peroxide

Concentration

>=50-<70 >=70% 50-<70% >=70% 50-<70% 35-<50% 8-<50% 5-<8% >=35%

General Information

Version

6.11

Revision date

2026-07-13

Product name

Hydrogen peroxide solution

Emergency telephone

+49 (0)696 43508409

Icons in SDS

GHS03 GHS05 GHS07 GHS09 M004 M009 M011

Company Information

company name

Sigma-Aldrich Chemie GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

technischerservice@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H272, H302, H314, H318, H335, H400, H410, H412

Hazard statements

Code

Statements

H272

May intensify fire; oxidiser

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger Danger

Hazard statements

H272 May intensify fire; oxidizer. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. H314 Causes severe skin burns and eye damage.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Response

P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Hazardous Ingredients

Hydrogen Peroxide Reduced Labelling (<= 125 ml)

Supplemental label elements

none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Oxidizing liquids, Category 2 H272: May intensify fire; oxidizer. Acute toxicity, Category 4 H302: Harmful if swallowed. Skin corrosion, Sub-category 1B H314: Causes severe skin burns and eye damage. Serious eye damage, Category 1 H318: Causes serious eye damage. Specific target organ toxicity - H335: May cause respiratory irritation. single exposure, Category 3, Respiratory system Short-term (acute) aquatic hazard, H400: Very toxic to aquatic life. Category 1 Long-term (chronic) aquatic hazard, H412: Harmful to aquatic life with long Category 3 lasting effects.

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