Note: Ingredients listed on restricted chemical lists
EC/CAS
10101-97-0
Name of the chemical
Nickel(II) sulfate hexahydrate (1:1:6)
Concentration
>=10-<=30
EC/CAS
67-56-1
Name of the chemical
Methanol
Concentration
>=3-<=7
EC/CAS
108-10-1
Name of the chemical
4-methylpentan-2-one; isobutyl methyl ketone (MIBK)
Concentration
>=0.1-<=1
General Information
Version
6.12
Revision date
2025-05-01
Product name
HIS-Select HF Nickel Affinity Gel
1.2.1 Relevant identified uses
Laboratory chemicals, Synthesis of substances
1.2.2. Uses advised against
The product is being supplied under the TSCA R&D Exemption
Emergency telephone
800-424-9300, +1-703- 527-3887
Icons in SDS
Company Information
company name
Sigma-Aldrich Inc
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H226, H302, H315, H317, H334, H341, H350, H360, H371, H372, H411
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Long term hazards
Category 2 aquatic hazard
Other hazards
None known
Signal word
Danger
Hazard statements
H226 Flammable liquid and vapor. H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H341 Suspected of causing genetic defects. H350 May cause cancer by inhalation. H360 May damage fertility or the unborn child. H371 May cause damage to organs (Eyes, Central nervous system). H372 Causes damage to organs (Respiratory Tract) through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects.
Prevention
P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe mist or vapors. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing must not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P280 Wear protective gloves, protective clothing, eye protection and face protection. P285 In case of inadequate ventilation wear respiratory protection.
Response
P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308 + P311 IF exposed or concerned: Call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER/ doctor. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391 Collect spillage.
Storage
P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.
Disposal
P501 Dispose of contents/ container to an approved waste disposal plant.
2.1 Classification of the substance or mixture
(29 CFR 1910.1200) Flammable liquids : Category 3 Acute toxicity (Oral) : Category 4 Skin irritation : Category 2 Respiratory sensitization : Category 1 Skin sensitization : Category 1 Germ cell mutagenicity : Category 2 Carcinogenicity : Category 1A (Inhalation) Reproductive toxicity : Category 1B Specific target organ : Category 2 (Eyes, Central nervous system) toxicity - single exposure Specific target organ : Category 1 (Respiratory Tract) toxicity - repeated exposure Short-term (acute) : Category 2 aquatic hazard Long-term (chronic) : Category 2 aquatic hazard Other hazards