Hexafluorophosphoric acid solution

Merck Life Science Pty Ltd

Revision date : 2026-07-14

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GHS06 GHS05
Health risk rating 5
Safety risk rating 5
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

7664-38-2

Name of the chemical

phosphoric acid

Concentration

>=3-<5

EC/CAS

7664-39-3

Name of the chemical

Hydrofluoric acid, its normal salts, its complexes and hydrofluorides with the exception of those given in Annex III

Concentration

>=3-<5

General Information

Version

6.7

Revision date

2026-07-14

Product name

Hexafluorophosphoric acid solution

1.2.1 Relevant identified uses

For R&D use only. Not for pharmaceutical, household or other uses

Emergency telephone

+61 2 9037 2994

Icons in SDS

GHS05 GHS06 M004 M008 M009 M011 M017

Company Information

company name

Merck Life Science Pty Ltd

e-mail address of the competent person responsible for the Safety Data Sheet

customersupport.anz@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H290, H301, H310, H314, H332

Hazard statements

Code

Statements

H290

May be corrosive to metals

Section 2

SECTION 2: Hazards identification

GHS Classification Corrosive to metals Category 1 Acute toxicity (Oral) Category 3 Acute toxicity (Inhalation) Category 4 Acute toxicity (Dermal) Category 2 Skin corrosion/irritation Sub-category 1B Serious eye damage/eye irritation Category 1

Signal word

Danger

Hazard statements

H290 May be corrosive to metals. H301 Toxic if swallowed. H310 Fatal in contact with skin. H314 Causes severe skin burns and eye damage. H332 Harmful if inhaled.

Prevention

P234 Keep only in original packaging. P261 Avoid breathing mist or vapours. P262 Do not get in eyes, on skin, or on clothing. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this prod- uct. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immedi- ately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cau- tiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P361 + P364 Take off immediately all contaminated clothing and wash it before reuse. P390 Absorb spillage to prevent material damage.

Storage

P405 Store locked up. P406 Store in a corrosion resistant container with a resistant inner liner.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

Strong hydrogen fluoride-releaser

2.1 Classification of the substance or mixture

Corrosive to metals : Category 1 Acute toxicity (Oral) : Category 3 Acute toxicity (Inhalation) : Category 4 Acute toxicity (Dermal) : Category 2 Skin corrosion/irritation : Sub-category 1B Serious eye damage/eye : Category 1 irritation

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