Guanidine hydrochloride solution

Merck Ltd.

Revision date : 2026-07-10

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GHS07
Health risk rating 3
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

200-002-3/50-01-1

Name of the chemical

Guanidinium chloride

Concentration

>=50-<70

Listed in

General Information

Version

6.7

Revision date

2026-07-10

Product name

Guanidine hydrochloride solution

Emergency telephone

+81 (0)3 4520 9637

Icons in SDS

GHS07 M004 M009 M011 M017

Company Information

company name

Merck Ltd.

GHS Information

Signal word

Warning

Hazard Codes

Hazard statements (CLP)

H302, H302+H332, H315, H319, H332

Hazard statements

Code

Statements

H302

Harmful if swallowed

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Warning Warning

Hazard statements

H302 + H332 Harmful if swallowed or if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. none

Precautionary statements

P261 Avoid breathing mist or vapours. P264 Wash skin thoroughly after handling. none

Response

P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Hazardous Ingredients

Guanidinium chloride Reduced Labelling (<= 125 ml)

Supplemental label elements

none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Acute toxicity, Category 4 H302: Harmful if swallowed. Acute toxicity, Category 4 H332: Harmful if inhaled. Skin irritation, Category 2 H315: Causes skin irritation. Eye irritation, Category 2 H319: Causes serious eye irritation.

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