Note: Ingredients listed on restricted chemical lists
EC/CAS
200-001-8/50-00-0
Name of the chemical
Formaldehyde
Concentration
>=30-<50
EC/CAS
200-659-6/67-56-1
Name of the chemical
Methanol
Concentration
>=10-<20 603-001-
General Information
Version
7.22
Revision date
2025-07-15
Product name
Formaldehyde solution about 37% GR for analysis stabilized with about 10% methanol ACS,Reag. Ph Eur
REACH No
This
1.2.1 Relevant identified uses
Reagent for analysis
Emergency telephone
+(44)-870-8200418, +(353)-19014670, 001-803-017-9114
Icons in SDS
Company Information
Company name
Merck KGaA
E-mail address of the competent person responsible for the Safety Data Sheet
TechnicalService@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H301, H301+H311, H311, H314, H317, H318, H330, H335, H341, H350, H370
Hazard statements
Code
Statements
H301
Toxic if swallowed
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture Acute toxicity, (Category 3) H301: Toxic if swallowed Acute toxicity, (Category 2) H330: Fatal if inhaled Acute toxicity, (Category 3) H311: Toxic in contact with skin Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage Serious eye damage, (Category H318: Causes serious eye damage Skin sensitisation, (Category 1) H317: May cause an allergic skin reaction Germ cell mutagenicity, H341: Suspected of causing genetic Category 2) defects Carcinogenicity, (Category 1B) H350: May cause cancer Specific target organ toxicity - H370: Causes damage to organs single exposure, (Category 1), Eyes, Central nervous system Specific target organ toxicity - H335: May cause respiratory irritation single exposure, (Category 3), Respiratory system Label elements
Signal word
Danger Danger
Hazard statements
H301 + H311 Toxic if swallowed or in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H330 Fatal if inhaled. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H350 May cause cancer. H370 Causes damage to organs (Eyes, Central nervous system). Restricted to professional users. Reduced Labelling (<= 125 ml) H330 Fatal if inhaled. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H350 May cause cancer. H370 Causes damage to organs. H314 Causes severe skin burns and eye damage. H301 + H311 Toxic if swallowed or in contact with skin.
Precautionary statements
P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe mist or vapours. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe mist or vapours. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental label elements
none none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
2.1 Classification of the substance or mixture
Acute toxicity, (Category 3) H301: Toxic if swallowed. Acute toxicity, (Category 2) H330: Fatal if inhaled. Acute toxicity, (Category 3) H311: Toxic in contact with skin. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Skin sensitisation, (Category 1) H317: May cause an allergic skin reaction. Germ cell mutagenicity, H341: Suspected of causing genetic (Category 2) defects. Carcinogenicity, (Category 1B) H350: May cause cancer. Specific target organ toxicity - H370: Causes damage to organs. single exposure, (Category 1), Eyes, Central nervous system Specific target organ toxicity - H335: May cause respiratory irritation. single exposure, (Category 3),