Formaldehyde solution 4%, buffered, pH 6.9

Merck KGaA

Revision date : 2024-11-09

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

200-001-8/50-00-0

Name of the chemical

Formaldehyde

Concentration

>=3-<5%

EC/CAS

200-659-6/67-56-1

Name of the chemical

Methanol

Concentration

>=1-<3% 603-001-

General Information

Version

7.14

Revision date

2024-11-09

Product name

Formaldehyde solution 4%, buffered, pH 6.9

REACH No

This

1.2.1 Relevant identified uses

In vitro diagnostic reagent, Reagent for analysis

Emergency telephone

+(44)-870-8200418, +(353)-19014670, 001-803-017-9114

Icons in SDS

GHS07 GHS08

Company Information

company name

Merck KGaA

e-mail address of the competent person responsible for the Safety Data Sheet

TechnicalService@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H302, H302+H332, H317, H332, H341, H350

Hazard statements

Code

Statements

H302

Harmful if swallowed

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture Acute toxicity, (Category 4) H302: Harmful if swallowed Acute toxicity, (Category 4) H332: Harmful if inhaled Skin sensitization, (Category H317: May cause an allergic skin reaction Germ cell mutagenicity, H341: Suspected of causing genetic Category 2) defects Carcinogenicity, (Category 1B) H350: May cause cancer

Signal word

Danger Danger

Hazard statements

H302 + H332 Harmful if swallowed or if inhaled. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H350 May cause cancer. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H350 May cause cancer.

Precautionary statements

P202 Do not handle until all safety precautions have been read and understood. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P202 Do not handle until all safety precautions have been read and understood. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302 + P352 IF ON SKIN: Wash with plenty of water. P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Supplemental label elements

none Restricted to professional users. Reduced Labeling (<= 125 ml) none

Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Acute toxicity, (Category 4) H302: Harmful if swallowed. Acute toxicity, (Category 4) H332: Harmful if inhaled. Skin sensitization, (Category 1) H317: May cause an allergic skin reaction. Germ cell mutagenicity, H341: Suspected of causing genetic (Category 2) defects. Carcinogenicity, (Category 1B) H350: May cause cancer.

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