Note: Ingredients listed on restricted chemical lists
EC/CAS
200-838-9/75-09-2
Name of the chemical
Methylene chloride
Concentration
>=10-<20 20%
General Information
Version
6.11
Revision date
2025-12-25
Product name
Ethyl diazoacetate
Emergency telephone
+49 (0)696 43508409
Icons in SDS
Company Information
company name
Sigma-Aldrich Chemie GmbH
e-mail address of the competent person responsible for the Safety Data Sheet
technischerservice@merckgroup.com
GHS Information
Signal word
Warning
Hazard Codes
Hazard statements (CLP)
H226, H242, H302, H315, H319, H351
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture
Signal word
Warning Warning
Hazard statements
H226 Flammable liquid and vapour. H242 Heating may cause a fire. H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H351 Suspected of causing cancer. H351 Suspected of causing cancer.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P308 + P313 IF exposed or concerned: Get medical advice/ attention.
Response
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Storage
P403 + P235 Store in a well-ventilated place. Keep cool.
Hazardous Ingredients
Ethyl diazoacetate Dichloromethane Reduced Labelling (<= 125 ml)
Supplemental label elements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 3 H226: Flammable liquid and vapour. Self-reactive substances and H242: Heating may cause a fire. mixtures, Type E Acute toxicity, Category 4 H302: Harmful if swallowed. Skin irritation, Category 2 H315: Causes skin irritation. Eye irritation, Category 2 H319: Causes serious eye irritation. Carcinogenicity, Category 2 H351: Suspected of causing cancer.