Divinylbenzene (stabilised with 4-tert- butylpyrocatechol) for synthesis

Hazard statements (CLP)

H227, H304, H315, H317, H319, H335, H361, H411

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

Aspiration hazard

Category 1 Long-term (chronic) Category 2 aquatic hazard Other hazards None known

Signal word

Danger

Hazard statements

H227 Combustible liquid. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H361 Suspected of damaging fertility or the unborn child. H411 Toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing mist or vapours. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P331 Do NOT induce vomiting. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

2.1 Classification of the substance or mixture

(29 CFR 1910.1200) Hazards for the product as supplied Flammable liquids : Category 4 Skin irritation : Category 2 Eye irritation : Category 2A Skin sensitisation : Sub-category 1B Reproductive toxicity : Category 2 Specific target organ : Category 3 (Respiratory system) toxicity - single exposure Aspiration hazard : Category 1 Long-term (chronic) : Category 2 aquatic hazard Other hazards