Note: Ingredients listed on restricted chemical lists
EC/CAS
200-838-9/75-09-2
Name of the chemical
Methylene chloride
Concentration
60-100%
General Information
Version
5.2
Revision date
2012-09-19
Product name
Diisobutylaluminum hydride solution
supplier name
Sigma-Aldrich
Emergency telephone
+1 800-325-5832, +1 800-325-5052, 1-800-521-8956
Icons in SDS
Company Information
company name
Sigma-Aldrich
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H250, H261, H302, H314, H351
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
NFPA Rating Emergency Overview
Signal word
Danger
Hazard statements
H225 Highly flammable liquid and vapour. H250 Catches fire spontaneously if exposed to air. H261 In contact with water releases flammable gases. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H351 Suspected of causing cancer.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P222 Do not allow contact with air. P231 + P232 Handle under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/ physician. P422 Store contents under inert gas.
Health hazards
3 * Flammability: 4 3 Fire: 3 Reactivity Hazard: 3
Physical hazards
3
Potential health effects
Inhalation May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Skin Harmful if absorbed through skin. Causes skin burns. Eyes Causes eye burns. Ingestion Harmful if swallowed.
2.1 Classification of the substance or mixture
Flammable liquids (Category 2) Pyrophoric liquids (Category 1) Substances, which in contact with water, emit flammable gases (Category 2) Acute toxicity, Oral (Category 4) Skin corrosion (Category 1A) Serious eye damage (Category 1) Carcinogenicity (Category 2)