Diethyl azodicarboxylate solution

Hazard statements (CLP)

H226, H242, H304, H315, H319, H335, H336, H361d, H373, H412

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger Danger

Hazard statements

H226 Flammable liquid and vapour. H242 Heating may cause a fire. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H361d Suspected of damaging the unborn child. H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure if inhaled. H412 Harmful to aquatic life with long lasting effects. H304 May be fatal if swallowed and enters airways. H412 Harmful to aquatic life with long lasting effects. H361d Suspected of damaging the unborn child.

Precautionary statements

Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P331 Do NOT induce vomiting.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P331 Do NOT induce vomiting. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool.

Hazardous Ingredients

Toluene Diethyl azodiformate Reduced Labelling (<= 125 ml)

Supplemental label elements

none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 3 H226: Flammable liquid and vapour. Self-reactive substances and H242: Heating may cause a fire. mixtures, Type C Skin irritation, Category 2 H315: Causes skin irritation. Eye irritation, Category 2 H319: Causes serious eye irritation. Reproductive toxicity, Category 2 H361d: Suspected of damaging the unborn child. Specific target organ toxicity - H335: May cause respiratory irritation. single exposure, Category 3, Respiratory system Specific target organ toxicity - H336: May cause drowsiness or dizziness. single exposure, Category 3, Central nervous system Specific target organ toxicity - H373: May cause damage to organs through repeated exposure, Category 2, prolonged or repeated exposure if inhaled. Central nervous system Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters airways. Long-term (chronic) aquatic hazard, H412: Harmful to aquatic life with long Category 3 lasting effects.