Crotonaldehyde (mixture of isomers) for synthesis

Merck KGaA

Revision date : 2018-08-30

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GHS02 GHS05 GHS06 GHS07 GHS08 GHS09
Health risk rating 5
Safety risk rating 3
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

4170-30-3

Name of the chemical

Crotonaldehyd; 2-Butenal (E)-2-Butenal; (E)-Crotonaldehyd

Concentration

N/A

EC/CAS

224-030-0

Name of the chemical

Crotonaldehyd; 2-Butenal (E)-2-Butenal; (E)-Crotonaldehyd

Concentration

N/A

General Information

Revision date

2018-08-30

Product name

Crotonaldehyde (mixture of isomers) for synthesis

CAS No.

4170-30-3

REACH No

is

Emergency telephone

Customer Call Centre: + 62 0800 140 1253 (Toll Free

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Company Information

company name

Merck KGaA

e-mail address of the competent person responsible for the Safety Data Sheet

prodsafe@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H301, H311, H315, H318, H330, H335, H341, H373, H400

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

EU Classification

CLASS regulations 2013 Flammable liquid, Category 2, H225 Germ cell mutagenicity, Category 2, H341 Acute toxicity, Category 2, Inhalation, H330 Acute toxicity, Category 3, Dermal, H311 Acute toxicity, Category 3, Oral, H301 Specific target organ toxicity - repeated exposure, Category 2, H373 Specific target organ toxicity - single exposure, Category 3, Respiratory system, H335 Skin irritation, Category 2, H315 Serious eye damage, Category 1, H318 Acute aquatic toxicity, Category 1, H400 For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according to CLASS regulations 2013

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapour. H341 Suspected of causing genetic defects. H330 Fatal if inhaled. H311 Toxic in contact with skin. H301 Toxic if swallowed. H373 May cause damage to organs through prolonged or repeated exposure. H335 May cause respiratory irritation. H315 Causes skin irritation. H318 Causes serious eye damage. H400 Very toxic to aquatic life. H341 Suspected of causing genetic defects. H330 Fatal if inhaled. H311 Toxic in contact with skin. H301 Toxic if swallowed. H318 Causes serious eye damage.

Prevention

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P273 Avoid release to the environment.

Response

P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.

Storage

P403 + P235 Store in a well-ventilated place. Keep cool. Reduced labelling (≤125 ml)

Precautionary statements

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician. CAS-No. 4170-30-3

2.3 Other hazards

None known.

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