Crotonaldehyde (mixture of isomers) for synthesis

Merck KGaA

Revision date : 2022-11-25

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GHS02 GHS05 GHS06 GHS07 GHS08 GHS09
Health risk rating 5
Safety risk rating 3
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

224-030-0/4170-30-3

Name of the chemical

Crotonaldehyd; 2-Butenal (E)-2-Butenal; (E)-Crotonaldehyd

Concentration

N/A

General Information

Revision date

2022-11-25

Product name

Crotonaldehyde (mixture of isomers) for synthesis

CAS No.

4170-30-3

REACH No

is

Emergency telephone

+(44)-870-8200418 (CHEMTREC (GB

Icons in SDS

GHS02 GHS06 GHS09

Company Information

company name

Merck KGaA

e-mail address of the competent person responsible for the Safety Data Sheet

TechnicalService@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H301, H301+H311, H311, H315, H318, H330, H335, H341, H373, H400

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

CLP CLASSIFICATION

Flammable liquids (Category 2), H225 Acute toxicity, Oral (Category 3), H301 Acute toxicity, Inhalation (Category 2), H330 Acute toxicity, Dermal (Category 3), H311 Skin irritation (Category 2), H315 Serious eye damage (Category 1), H318 Germ cell mutagenicity (Category 2), H341 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Specific target organ toxicity - repeated exposure (Category 2), H373 Short-term (acute) aquatic hazard (Category 1), H400 For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapor. H301 + H311 Toxic if swallowed or in contact with skin. H315 Causes skin irritation. H318 Causes serious eye damage. H330 Fatal if inhaled. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. Reduced Labeling (<= 125 ml) H330 Fatal if inhaled. H341 Suspected of causing genetic defects. H318 Causes serious eye damage. H301 + H311 Toxic if swallowed or in contact with skin.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental label elements

none none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

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