Chromium(VI) oxide for synthesis

Merck Life Science N.V

Revision date : 2025-06-26

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GHS09 GHS06 GHS03 GHS08
Health risk rating 5
Safety risk rating 4
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

215-607-8/1333-82-0

Name of the chemical

Chromium trioxide

Concentration

chromium trioxide Included in the Candidate List of Substance...

General Information

Version

6.19

Revision date

2025-06-26

Product name

Chromium(VI) oxide for synthesis

CAS No.

1333-82-0

REACH No

A

Emergency telephone

+(31)-858880596

Icons in SDS

GHS03 GHS06 GHS08 GHS09

Company Information

Company name

Merck Life Science N.V

E-mail address of the competent person responsible for the Safety Data Sheet

technischeservicebenelux@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H271, H301, H301+H311, H311, H314, H317, H318, H330, H334, H335, H340, H350, H361f, H372, H400, H410

Hazard statements

Code

Statements

H271

May cause fire or explosion; strong oxidiser

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture Oxidizing solids, (Category 1) H271: May cause fire or explosion; strong oxidizer Acute toxicity, (Category 3) H301: Toxic if swallowed Acute toxicity, (Category 2) H330: Fatal if inhaled Acute toxicity, (Category 3) H311: Toxic in contact with skin Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1A) damage Serious eye damage, (Category H318: Causes serious eye damage Respiratory sensitisation, H334: May cause allergy or asthma Category 1) symptoms or breathing difficulties if inhaled Skin sensitisation, (Category 1) H317: May cause an allergic skin reaction Germ cell mutagenicity, H340: May cause genetic defects Category 1B) Carcinogenicity, (Category 1A) H350: May cause cancer Reproductive toxicity, (Category H361f: Suspected of damaging fertility Specific target organ toxicity - H335: May cause respiratory irritation single exposure, (Category 3), Respiratory system Specific target organ toxicity - H372: Causes damage to organs through repeated exposure, (Category 1) prolonged or repeated exposure if inhaled Short-term (acute) aquatic H400: Very toxic to aquatic life hazard, (Category 1) Long-term (chronic) aquatic H410: Very toxic to aquatic life with long hazard, (Category 1) lasting effects

Signal word

Danger Danger

Hazard statements

H271 May cause fire or explosion; strong oxidizer. H301 + H311 Toxic if swallowed or in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H330 Fatal if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H340 May cause genetic defects. H350 May cause cancer. H361f Suspected of damaging fertility. H372 Causes damage to organs through prolonged or repeated exposure if inhaled. H410 Very toxic to aquatic life with long lasting effects. Restricted to professional users. Reduced Labelling (<= 125 ml) H271 May cause fire or explosion; strong oxidizer. H330 Fatal if inhaled. H317 May cause an allergic skin reaction. H340 May cause genetic defects. H350 May cause cancer. H372 Causes damage to organs through prolonged or repeated exposure if inhaled. H314 Causes severe skin burns and eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H361f Suspected of damaging fertility. H301 + H311 Toxic if swallowed or in contact with skin.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental label elements

none none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Oxidizing solids, (Category 1) H271: May cause fire or explosion; strong oxidizer. Acute toxicity, (Category 3) H301: Toxic if swallowed. Acute toxicity, (Category 2) H330: Fatal if inhaled. Acute toxicity, (Category 3) H311: Toxic in contact with skin. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1A) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Respiratory sensitisation, H334: May cause allergy or asthma (Category 1) symptoms or breathing difficulties if inhaled. Skin sensitisation, (Category 1) H317: May cause an allergic skin reaction. Germ cell mutagenicity, H340: May cause genetic defects. (Category 1B) Carcinogenicity, (Category 1A) H350: May cause cancer. Reproductive toxicity, (Category H361f: Suspected of damaging fertility. 2) Specific target organ toxicity - H335: May cause respiratory irritation. single exposure, (Category 3), Respiratory system Specific target organ toxicity - H372: Causes damage to organs through repeated exposure, (Category 1) prolonged or repeated exposure if inhaled. Short-term (acute) aquatic H400: Very toxic to aquatic life. hazard, (Category 1) Long-term (chronic) aquatic H410: Very toxic to aquatic life with long hazard, (Category 1) lasting effects.

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