Note: Ingredients listed on restricted chemical lists
EC/CAS
215-607-8/1333-82-0
Name of the chemical
Chromium trioxide
Concentration
100%
General Information
Version
19.0
Revision date
2011-05-17
Product name
Chromium(VI) oxide for synthesis
CAS No.
1333-82-0
REACH No
is
Emergency telephone
Please contact the regional company representation in your country
Icons in SDS
Company Information
company name
Merck KGaA
e-mail address of the competent person responsible for the Safety Data Sheet
prodsafe@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H271, H301, H301+H311, H311, H314, H317, H330, H334, H335, H340, H350, H361f, H372, H400, H410
Hazard statements
Code
Statements
H271
May cause fire or explosion; strong oxidiser
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification
Signal word
Danger Danger
Hazard statements
H271 May cause fire or explosion; strong oxidiser. H350 May cause cancer. H340 May cause genetic defects. H361f Suspected of damaging fertility. H330 Fatal if inhaled. H301 + H311 Toxic if swallowed or in contact with skin. H372 Causes damage to organs through prolonged or repeated exposure. H314 Causes severe skin burns and eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. H271 May cause fire or explosion; strong oxidiser. H350 May cause cancer. H340 May cause genetic defects. H361f Suspected of damaging fertility. H330 Fatal if inhaled. H301 + H311 Toxic if swallowed or in contact with skin. H372 Causes damage to organs through prolonged or repeated exposure. H314 Causes severe skin burns and eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction.
Precautionary statements
P201 Obtain special instructions before use. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. Restricted to professional users. Reduced labelling (≤125 ml) P201 Obtain special instructions before use. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. Restricted to professional users. Index-No. 024-001-00-0
2.2 Label elements
67/548/EEC or 1999/45/EC)
Hazard pictograms
O Oxidising T+ Very toxic N Dangerous for the environment O Oxidising T+ Very toxic N Dangerous for the environment
R-phrase(s)
45-46-9-24/25-26- May cause cancer. May cause heritable genetic damage. 35-42/43-48/23- Explosive when mixed with combustible material. Also toxic 50/53-62 in contact with skin and if swallowed. Also very toxic by inhalation. Causes severe burns. May cause sensitization by inhalation and skin contact. Also toxic: danger of serious damage to health by prolonged exposure through inhalation. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risk of impaired fertility. 45-46-24/25-26-35-42/43- May cause cancer. May cause heritable genetic damage. Also toxic in 48/23-62 contact with skin and if swallowed. Also very toxic by inhalation. Causes severe burns. May cause sensitization by inhalation and skin contact. Also toxic: danger of serious damage to health by prolonged exposure through inhalation. Possible risk of impaired fertility.
S-phrase(s)
53-45-60-61 Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/ Safety data sheets. 53-45 Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Further information
Restricted to professional users. EC-No. 215-607-8 EC Label Reduced labelling (≤125 ml)
2.3 Other hazards
None known.