Butyllithium (15% solution in n-hexane) for synthesis

Hazard statements (CLP)

H225, H250, H260, H304, H314, H318, H336, H361f, H373, H411

Code

Statements

H225

Highly Flammable liquid and vapour

CLP CLASSIFICATION

Flammable liquids (Category 2), H225 Pyrophoric liquids (Category 1), H250 Substances and mixtures which in contact with water emit flammable gases (Category 1), H260 Skin corrosion (Sub-category 1B), H314 Serious eye damage (Category 1), H318 Reproductive toxicity (Category 2), H361f Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336 Specific target organ toxicity - repeated exposure, Inhalation (Category 2), Nervous system, H373

Aspiration hazard

Category 1), H304 Long-term (chronic) aquatic hazard (Category 2), H411 For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapor. H250 Catches fire spontaneously if exposed to air. H260 In contact with water releases flammable gases which may ignite spontaneously. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness. H361f Suspected of damaging fertility. H373 May cause damage to organs (Nervous system) through prolonged or repeated exposure if inhaled. H411 Toxic to aquatic life with long lasting effects. H250 Catches fire spontaneously if exposed to air. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H361f Suspected of damaging fertility.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Supplemental label elements

EUH014 Reacts violently with water. Reduced Labeling (<= 125 ml) EUH014 Reacts violently with water.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.